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/content/aip/journal/aplmater/3/2/10.1063/1.4906880
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/content/aip/journal/aplmater/3/2/10.1063/1.4906880
2015-02-03
2016-09-27

Abstract

We demonstrate the growth of high quality single phase films of VO(A, B, and M) on SrTiO substrate by controlling the vanadium arrival rate (laser frequency) and oxidation of the V atoms. A phase diagram has been developed (oxygen pressure versus laser frequency) for various phases of VO and their electronic properties are investigated. VO(A) phase is insulating VO(B) phase is semi-metallic, and VO(M) phase exhibits a metal-insulator transition, corroborated by photo-electron spectroscopic studies. The ability to control the growth of various polymorphs opens up the possibility for novel (hetero)structures promising new device functionalities.

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