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/content/aip/journal/aplmater/3/7/10.1063/1.4927232
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/content/aip/journal/aplmater/3/7/10.1063/1.4927232
2015-07-24
2016-12-09

Abstract

Chirality, i.e., handedness, pervades much of modern science from elementary particles, DNA-based biology to molecular chemistry; however, most of the chirality-relevant materials have been based on complex molecules. Here, we report inorganic single-crystalline Ni TeO, forming in a corundum-related 3 structure with both chirality and polarity. These chiral Ni TeO single crystals exhibit a large optical specific rotation ()—1355° dm−1 cm3 g−1. We demonstrate, for the first time, that in Ni TeO, chiral and polar domains form an intriguing domain pattern, resembling a radiation warning sign, which stems from interlocked chiral and polar domain walls through lowering of the wall energy.

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