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/content/aip/journal/aplmater/4/10/10.1063/1.4953439
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See supplementary material at http://dx.doi.org/10.1063/1.4953439 for Figs. S1 and S2.[Supplementary Material]
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/content/aip/journal/aplmater/4/10/10.1063/1.4953439
2016-06-22
2016-09-25

Abstract

In this study, a series of copper sulfides Cu S with spanning from 1.8 to 1.96 was prepared and their crystal structures, elemental valence states, and thermoelectric properties were systematically studied. The valence state of Cu in Cu S is unchanged as the ratio of Cu/S varies, while the thermoelectric properties are very sensitive to the deficiency of Cu. In addition, the type of sulfur arrangement in the crystal structure also plays an important role on the electrical transports. Finally, the optimum Cu/S atomic ratios in the binary Cu S system were identified for high power factor and thermoelectric figure of merit.

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