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1.
1.A. Kojima, K. Teshima, Y. Shirai, and T. Miyasaka, J. Am. Chem. Soc. 131, 60506051 (2009).
http://dx.doi.org/10.1021/ja809598r
2.
2.M. A. Green, K. Emery, Y. Hishikawa, W. Warta, and E. D. Dunlop, “Solar cell efficiency tables (Version 45),” Prog. Photovoltaics 23, 19 (2015).
http://dx.doi.org/10.1002/pip.2573
3.
3.M. Liu, M. B. Johnston, and H. J. Snaith, Nature 501, 395398 (2013).
http://dx.doi.org/10.1038/nature12509
4.
4.J. Burschka, N. Pellet, S.-J. Moon, R. Humphry-Baker, P. Gao, M. K. Nazeeruddin, and M. Grätzel, Nature 499, 316319 (2013).
http://dx.doi.org/10.1038/nature12340
5.
5.G. Hodes and D. Cahen, Nat. Photonics 8, 8788 (2014).
http://dx.doi.org/10.1038/nphoton.2014.5
6.
6.M. A. Green, A. Ho-Baillie, and H. J. Snaith, Nat. Photonics 8, 506514 (2014).
http://dx.doi.org/10.1038/nphoton.2014.134
7.
7.N. K. Noel, S. D. Stranks, A. Abate, C. Wehrenfennig, S. Guarnera, A. Haghighirad, A. Sadhanala, G. E. Eperon, S. K. Pathak, M. B. Johnston, A. Petrozza, L. Herz, and H. Snaith, Energy Environ. Sci. 7, 30613068 (2014).
http://dx.doi.org/10.1039/C4EE01076K
8.
8.F. Hao, C. C. Stoumpos, D. H. Cao, R. P. H. Chang, and M. G. Kanatzidis, Nat. Photonics 8, 489494 (2014).
http://dx.doi.org/10.1038/nphoton.2014.82
9.
9.C. C. Stoumpos, L. Fraser, D. J. Clark, Y. S. Kim, S. H. Rhim, A. J. Freeman, J. B. Ketterson, J. I. Jang, and M. G. Kanatzidis, J. Am. Chem. Soc. 137, 68046819 (2015).
http://dx.doi.org/10.1021/jacs.5b01025
10.
10.W. Zhang and R. G. Xiong, Chem. Rev. 112, 11631195 (2012).
http://dx.doi.org/10.1021/cr200174w
11.
11.P. Jain, N. S. Dalal, B. H. Toby, H. W. Kroto, and A. K. Cheetham, J. Am. Chem. Soc. 130, 1045010451 (2008).
http://dx.doi.org/10.1021/ja801952e
12.
12.S. L. Gorbach, Gastroenterology 99, 863875 (1990), available at http://www.gastrojournal.org/article/0016-5085(90)90983-8/pdf.
13.
13.See supplementary material at http://dx.doi.org/10.1063/1.4943680 for experimental details, additional data and figures.[Supplementary Material]
14.
14.P. Szklarz, A. Pietraszko, R. Jakubas, G. Bator, P. Zieliński, and M. Gałazka, J. Phys.: Condens. Matter 20, 255221 (2008).
http://dx.doi.org/10.1088/0953-8984/20/25/255221
15.
15.B. Chabot and E. Parthe, Acta Crystallogr., Sect. B: Struct. Crystallogr. Cryst. Chem. 34, 645648 (1978).
http://dx.doi.org/10.1107/S0567740878003684
16.
16.D. B. Mitzi, in Progress in Inorganic Chemistry, edited by K. D. Karlin (Wiley, New York, 1999), Vol. 38, Chap. 1.
17.
17.I. C. Smith, E. T. Hoke, D. Solis-Ibarra, M. D. McGehee, and H. I. Karunadasa, Angew. Chem., Int. Ed. 53, 1123211235 (2014).
http://dx.doi.org/10.1002/anie.201406466
18.
18.R. Deblieck, G. Van Tendeloo, J. Van Landuyt, and S. Amelinckx, Acta Crystallogr., Sect. B: Struct. Sci. 41, 319329 (1985).
http://dx.doi.org/10.1107/S010876818500221X
19.
19.H. M. Gladney and G. B. Street, J. Inorg. Nucl. Chem. 30, 29492953 (1968).
http://dx.doi.org/10.1016/0022-1902(68)80154-X
20.
20.V. I. Sidey, Y. V. Voroshilov, S. V. Kun, and E. Y. Peresh, J. Alloys Compd. 296, 5358 (2000).
http://dx.doi.org/10.1016/S0925-8388(99)00481-8
21.
21.A. J. Lehner, D. H. Fabini, H. A. Evans, C.-A. Hébert, S. R. Smock, J. Hu, H. Wang, J. W. Zwanziger, M. L. Chabinyc, and R. Seshadri, Chem. Mater. 27, 71377148 (2015).
http://dx.doi.org/10.1021/acs.chemmater.5b03147
22.
22.H. Zhang, L. Fang, and R.-Z. Yuan, Acta Crystallogr., Sect. E: Struct. Rep. Online 61, i70i72 (2005).
http://dx.doi.org/10.1107/S1600536805011098
23.
23.K. Yamada, H. Sera, S. Sawada, H. Tada, T. Okuda, and H. Tanaka, J. Solid State Chem. 134, 319325 (1997).
http://dx.doi.org/10.1006/jssc.1997.7562
24.
24.B. Saparov, F. Hong, J.-P. Sun, H.-S. Duan, W. Meng, S. Cameron, I. G. Hill, Y. Yan, and D. B. Mitzi, Chem. Mater. 27, 56225632 (2015).
http://dx.doi.org/10.1021/acs.chemmater.5b01989
25.
25.B.-W. Park, B. Philippe, X. Zhang, H. Rensmo, G. Boschloo, and E. M. J. Johansson, Adv. Mater. 27, 68066813 (2015).
http://dx.doi.org/10.1002/adma.201501978
26.
26.R. Hoye, R. E. Brandt, A. Osherov, V. Stevanovic, S. D. Stranks, M. W. B. Wilson, H. Kim, A. J. Akey, R. C. Kurchin, J. R. Poindexter, E. N. Wang, M. G. Bawendi, V. Bulovic, and T. Buonassisi, Chem. - Eur. J. 22, 26052610 (2016).
http://dx.doi.org/10.1002/chem.201505055
27.
27.O. V. Dolomano, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann, J. Appl. Crystallogr. 42, 339341 (2009).
http://dx.doi.org/10.1107/s0021889808042726
28.
28.G. M. Sheldrick, Acta Crystallogr Sect. A: Found. Adv. 71, 38 (2015).
http://dx.doi.org/10.1107/S2053273314026370
29.
29.G. M. Sheldrick, Acta Crystallogr Sect. A: Found. Adv. 64, 112122 (2008).
http://dx.doi.org/10.1107/S0108767307043930
30.
30.P. E. Blöchl, Phys. Rev. B 50, 1795317979 (1994).
http://dx.doi.org/10.1103/PhysRevB.50.17953
31.
31.G. Kresse and D. Joubert, Phys. Rev. B 59, 17581775 (1999).
http://dx.doi.org/10.1103/PhysRevB.59.1758
32.
32.G. Kresse and J. Hafner, Phys. Rev. B 47, 558561 (1993).
http://dx.doi.org/10.1103/PhysRevB.47.558
33.
33.G. Kresse and J. Hafner, Phys. Rev. B 49, 1425114269 (1994).
http://dx.doi.org/10.1103/PhysRevB.49.14251
34.
34.G. Kresse, Phys. Rev. B 54, 1116911186 (1996).
http://dx.doi.org/10.1103/PhysRevB.54.11169
35.
35.G. Kresse and J. Furthmüller, Comput. Mater. Sci. 6, 1550 (1996).
http://dx.doi.org/10.1016/0927-0256(96)00008-0
36.
36.A. Tkatchenko and M. Scheffler, Phys. Rev. Lett. 102, 073005 (2009).
http://dx.doi.org/10.1103/PhysRevLett.102.073005
37.
37.J. D. Pack and H. J. Monkhorst, Phys. Rev. B 16, 17481749 (1977).
http://dx.doi.org/10.1103/PhysRevB.16.1748
38.
38.C. Elsässer, M. Fähnle, C. T. Chan, and K. M. Ho, Phys. Rev. B 49, 1397513978 (1994).
http://dx.doi.org/10.1103/PhysRevB.49.13975
39.
39.K. Momma and F. Izumi, J. Appl. Crystallogr. 41, 653658 (2008).
http://dx.doi.org/10.1107/S0021889808012016
40.
40.S. Tominaka, H. Hamoudi, T. Suga, T. D. Bennett, A. B. Cairns, and A. K. Cheetham, Chem. Sci. 6, 14651473 (2015).
http://dx.doi.org/10.1039/C4SC03295K
41.
41.S. Tominaka, S. Henke, and A. K. Cheetham, CrystEngComm 15, 94009407 (2013).
http://dx.doi.org/10.1039/c3ce41150h
42.
42.S. Tominaka and A. K. Cheetham, RSC Adv. 4, 5438254387 (2014).
http://dx.doi.org/10.1039/C4RA11473F
43.
43.L. Dimesso, M. Dimamy, M. Hamburger, and W. Jaegermann, Chem. Mater. 26, 67626770 (2014).
http://dx.doi.org/10.1021/cm503240k
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/content/aip/journal/aplmater/4/3/10.1063/1.4943680
2016-03-15
2016-09-26

Abstract

Organic-inorganic halide perovskites, especially methylammonium lead halide, have recently led to remarkable advances in photovoltaic devices. However, due to environmental and stability concerns around the use of lead, research into lead-free perovskitestructures has been attracting increasing attention. In this study, a layered perovskite-like architecture, (NH)BiI, is prepared from solution and the structure solved by single crystalX-ray diffraction. The band gap, which is estimated to be 2.04 eV using UV-visible spectroscopy, is lower than that of CHNHPbBr. The energy-minimized structure obtained from first principles calculations is in excellent agreement with the X-ray results and establishes the locations of the hydrogen atoms. The calculations also point to a significant lone pair effect on the bismuth ion. Single crystal and powder conductivity measurements are performed to examine the potential application of (NH)BiI as an alternative to the lead containing perovskites.

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