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Nucleation energetics during homogeneous solidification in elemental metallic liquids
8.D. A. Porter and K. E. Easterling, Phase Transformations in Metals and Alloys, 2nd ed. (Chapman and Hall, London, 1992).
9.J. Christian, The Theory of Transformations in Metals and Alloys: An Advanced Textbook in Physical Metallurgy (Pergamon, Oxford, 1965).
10.K. F. Kelton, Crystal Nucleation in Liquids and Gases, Advances in Research and Applications Vol. 45 (Academic, New York, 1991), Chap. 2, pp. 75–178.
17.D. G. Fahrenheit, Philos. Trans. R. Soc. London 33, 78 (1724).
22.P. G. Debenedetti, Metastable Liquids (Princeton University Press, Princeton, 1996), Chap. 3, pp. 147–234.
24.Smithells Metals Reference Book, 8th ed., edited by W. Gale and T. Totemeier (Elsevier, New York, 2004).
26.A. V. Gorshkov, Inorg. Mater. 36, 218 (2000).
27.S. Blair, Int. Mater. Rev. 52, 323 (2007).
29.W. E. Frazier, “Empirical and Semi-Empirical Relationships of Liquid-Vapor, Solid-Vapor, and Solid-Liquid Surface Energies,” Naval Air Warfare Center, Aircraft Division Warminster, Technical Report No. 18974-0591, 1993.
31.P. -F. Paradis, T. Ishikawa, and S. Yoda, J. Math. Sci. (N.Y.) 36, 5125 (2001).
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The solidification of a liquid by nucleation is an important first order phase transition process. It is known that in order for elemental liquids to solidify homogeneously, it is necessary to supercool the liquid to a characteristic temperature below the thermodynamic melting point . Approximately 60 years ago Turnbull [J. Appl. Phys.21, 1022 (1950)] established the empirical rule that is approximately given by for several elemental metallic liquids. We show here that the magnitude of and for the metals can be accurately predicted from classical nucleation theory (CNT) provided the excess volume resulting from the density difference between liquid and solid be accounted for. Specifically, the density change accompanying the formation of a microscopic nucleus of the solid from the liquid results in a volume change in the surrounding liquid. When this is included in the free energy calculations within CNT, the resulting predictions for and for several metals with ranging from to 2900 K are in very good agreement with experimental measurements. This theory also shows that there is a universal character in the minimum nucleation barrier energy and the critical radius. The minimum barrier energy occurs at temperature for all the elemental liquids investigated, while the temperature dependencies of the barrier energy and the critical radius appear identical when expressed as a function of the scaled temperature .
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