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Magnetic susceptibilities, crystal field Stark energies, and hyperfine behavior of in hexagonal single crystals of
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10.1063/1.3093958
/content/aip/journal/jap/105/6/10.1063/1.3093958
http://aip.metastore.ingenta.com/content/aip/journal/jap/105/6/10.1063/1.3093958

Figures

Image of FIG. 1.
FIG. 1.

Variation of the effective magnetic moment of in as a function of temperature.

Image of FIG. 2.
FIG. 2.

Curie–Weiss simulation of the observed average susceptibility of .

Image of FIG. 3.
FIG. 3.

Thermal variations of experimental and theoretical magnetic susceptibilities ( and ) of in .

Image of FIG. 4.
FIG. 4.

Room temperature Raman Spectra of in SmTFMS observed in the wave number range of .

Image of FIG. 5.
FIG. 5.

Room temperature FTIR spectra of in SmTFMS recorded in the wave number range of ( indicates the CF Stark energies).

Image of FIG. 6.
FIG. 6.

Temperature dependence of computed electronic heat capacity of SmTFMS.

Image of FIG. 7.
FIG. 7.

Thermal variations of nuclear quadrupole splittings of and in .

Image of FIG. 8.
FIG. 8.

Temperature dependences of the hyperfine heat capacities of and in .

Tables

Generic image for table
Table I.

Calculated and observed CF Stark energies of the ground term of the ion in SmTFMS and its ground state wave functions (all the states are doublet).

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/content/aip/journal/jap/105/6/10.1063/1.3093958
2009-03-26
2014-04-21
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Magnetic susceptibilities, crystal field Stark energies, and hyperfine behavior of Sm3+ in hexagonal single crystals of Sm(CF3SO3)3⋅9H2O
http://aip.metastore.ingenta.com/content/aip/journal/jap/105/6/10.1063/1.3093958
10.1063/1.3093958
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