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Energy levels and symmetry assignments for Stark components of in yttrium gallium garnet
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10.1063/1.3259441
/content/aip/journal/jap/106/11/10.1063/1.3259441
http://aip.metastore.ingenta.com/content/aip/journal/jap/106/11/10.1063/1.3259441

Figures

Image of FIG. 1.
FIG. 1.

The 8 K absorption spectrum of the manifold observed between 1825 and 1975 nm. A hot band with structure to the right of 1930 nm represents transitions from the excited Stark level at .

Image of FIG. 2.
FIG. 2.

The 8 K absorption spectrum of the , multiplet manifolds observed between 532 and 545 nm. Relatively weak hot bands appear to the right of 540 and 542 nm.

Image of FIG. 3.
FIG. 3.

The 8 K absorption spectrum of the manifold. Note the separation between the two groups of GSA. To the right of 640 and 645 nm are several relatively weak hot bands representing transitions from the excited Stark level at .

Image of FIG. 4.
FIG. 4.

A survey spectrum of the 8 K absorption observed between 350 and 395 nm.

Image of FIG. 5.
FIG. 5.

The fluorescence spectrum at 78 K representing transitions from the Stark levels in the manifold to the ground-state manifold . Peaks to the left of the peak labeled “1” represent transitions to the 43, 30, 5, and Stark levels of . The experimental energy and irreps shown in the energy-level scheme are found in Table III.

Image of FIG. 6.
FIG. 6.

Fluorescence observed from the to and to between 740 and 770 nm at 293 K. The energy level structure and symmetry label assignments are given in Table III.

Tables

Generic image for table
Table I.

Wave function symmetries corresponding to each of the irreps.

Generic image for table
Table II.

Atomic and crystal-field energy parameters for the six different orientations of in YGG.

Generic image for table
Table III.

Calculated and experimentally observed energy levels for in YGG, along with irrep identifiers and largest wave function component for each energy level.

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/content/aip/journal/jap/106/11/10.1063/1.3259441
2009-12-11
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Energy levels and symmetry assignments for Stark components of Ho3+(4f10) in yttrium gallium garnet (Y3Ga5O12)
http://aip.metastore.ingenta.com/content/aip/journal/jap/106/11/10.1063/1.3259441
10.1063/1.3259441
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