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Hard x-ray photoemission spectroscopic investigation of palladium catalysts immobilized on a GaAs(001) surface
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10.1063/1.3456507
/content/aip/journal/jap/108/2/10.1063/1.3456507
http://aip.metastore.ingenta.com/content/aip/journal/jap/108/2/10.1063/1.3456507
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Valence band spectra from used-PSGA (after the tenth run of the Heck reaction), fresh-PSGA, SGA, GaAs, and the bulk Pd reference. Thin curve is calculated from the spectrum of used-PSGA by subtracting that of SGA so as to the band at 7 eV vanishes.

Image of FIG. 2.
FIG. 2.

spectra from used-PSGA (after the tenth run of the Heck reaction), fresh-PSGA, the bulk Pd reference, and the powder. Vertical lines are given at the position of peaks to make the shift and the asymmetry more visible.

Image of FIG. 3.
FIG. 3.

spectra from used-PSGA (after a tenth run of the Heck reaction), fresh-PSGA, SGA, and .

Image of FIG. 4.
FIG. 4.

(a) SEM image of the surface of fresh-PSGA. (b) BEI image of the same area of (a).

Image of FIG. 5.
FIG. 5.

(a) SEM image of the surface of used-PSGA. (b) BEI image of the same area of (a).

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/content/aip/journal/jap/108/2/10.1063/1.3456507
2010-07-27
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Hard x-ray photoemission spectroscopic investigation of palladium catalysts immobilized on a GaAs(001) surface
http://aip.metastore.ingenta.com/content/aip/journal/jap/108/2/10.1063/1.3456507
10.1063/1.3456507
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