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Raman spectroscopic study of Na1/2Bi1/2TiO3-x%BaTiO3 single crystals as a function of temperature and composition
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10.1063/1.3587236
/content/aip/journal/jap/109/11/10.1063/1.3587236
http://aip.metastore.ingenta.com/content/aip/journal/jap/109/11/10.1063/1.3587236
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Phase diagram of (Na1/2Bi1/2)TiO3-BaTiO3 (NBT-BT) solid solution (F α : Ferroelectric rhombohedral phase, F β : Ferroelectric tetragonal phase, AF: Antiferroelectric phase, P: Paraelectric phase Reprinted with permission from ref. 2. Copyright [1991], APEX/JJAP.).2

Image of FIG. 2.
FIG. 2.

(Color online) Temperature-dependent Raman spectra of (a) NBT and (b) NBT-5.6%BT from 25 °C to 600 °C.

Image of FIG. 3.
FIG. 3.

(Color online) Raman spectra of [(a) and (c)] (Na1/2Bi1/2)TiO3 (NBT) and [(b) and (d)] NBT-5.6%BT at 25 °C (left column) and 600 °C (right column) and the spectra deconvolution.

Image of FIG. 4.
FIG. 4.

(Color online) Peak position as a function of temperature of NBT.

Image of FIG. 5.
FIG. 5.

Integrated Intensity of the B-O peaks of (a) NBT and (b) NBT-5.6%BT as a function of temperature.

Image of FIG. 6.
FIG. 6.

Integrated Intensity of the A-O peaks of NBT as a function of temperature.

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/content/aip/journal/jap/109/11/10.1063/1.3587236
2011-06-01
2014-04-21
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Raman spectroscopic study of Na1/2Bi1/2TiO3-x%BaTiO3 single crystals as a function of temperature and composition
http://aip.metastore.ingenta.com/content/aip/journal/jap/109/11/10.1063/1.3587236
10.1063/1.3587236
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