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Addendum to “Phase selection and transition in Hf-rich hafnia-titania nanolaminates” (on SiO2) [J. Appl. Phys.109, 123523 (2011)]: Hafnon formation
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1.
1. M. C. Cisneros-Morales and C. R. Aita, Appl. Phys. Lett. 98, 051909 (2011).
http://dx.doi.org/10.1063/1.3551543
2.
2. M. C. Cisneros-Morales and C. R. Aita, J. Appl. Phys. 109, 123523 (2011).
http://dx.doi.org/10.1063/1.3597321
3.
3. M. C. Cisneros-Morales and C. R. Aita, J. Vac. Sci. Technol. 28, 1161 (2010).
http://dx.doi.org/10.1116/1.3474973
4.
4.Joint Commission on Powder Diffraction Standards Card No. 05-0565.
5.
5.Joint Commission on Powder Diffraction Standards Card No. 78-0050.
6.
6.Joint Commission on Powder Diffraction Standards Card No. 73-1765.
7.
7.Joint Commission on Powder Diffraction Standards Card No. 40-0794.
8.
8. J. Uhrmann and J. Pickardt, Z. Anorg. Chem. 532, 171 (1986); see also www-MINCRYST HAFNON-1835, http://database.iem.ac.ru/mincryst.
http://dx.doi.org/10.1002/zaac.19865320123
9.
9. A. Jayaraman, S. Y. Wang, S. K. Sharma, and L. C. Ming, Phys. Rev. B 48, 9205 (1993).
http://dx.doi.org/10.1103/PhysRevB.48.9205
10.
10. S. P. S. Porto, P. A. Fleury, and T. C. Damen, Phys. Rev. 154, 522 (1967).
http://dx.doi.org/10.1103/PhysRev.154.522
11.
11. M. A. Krebs and R. A. Condrate, Sr., J. Mater. Sci. Lett. 7, 1327 (1988).
http://dx.doi.org/10.1007/BF00719973
12.
12. J. H. Nicola and H. N. Rutt, J. Phys. C 7, 1381 (1974).
http://dx.doi.org/10.1088/0022-3719/7/7/029
13.
13. P. W. O. Hoskin and K. A. Rodgers, Eur. J. Solid State Inorg. Chem. 33, 1111 (1996).
14.
14. G.-M. Rignanese, X. Gonze, G. Jun, K. Cho, and A. Pasquarello, Phys. Rev. B 69, 184301 (2004).
http://dx.doi.org/10.1103/PhysRevB.69.184301
15.
15. B. Manoun, R. T. Downs, and S. K. Saxena, Am. Mineral. 91, 1888 (2006).
http://dx.doi.org/10.2138/am.2006.2070
16.
16. M. Gutowski, J. E. Jaffe, C.-L. Liu, M. Stoker, R. I. Hegde, R. S. Rai, and P. J. Tobin, Appl. Phys. Lett. 80, 1897 (2002).
http://dx.doi.org/10.1063/1.1458692
17.
17. D. Shin and Z.-K. Liu, Scr. Mater. 57, 201 (2007).
http://dx.doi.org/10.1016/j.scriptamat.2007.04.011
18.
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/content/aip/journal/jap/111/10/10.1063/1.4719968
2012-05-23
2014-09-22

Abstract

Continued investigation of hafnia-titania nanolaminates on silica substrates after long term annealing shows that hafnon (HfSiO4) is formed, in addition to the previously reported phases. Here, a 293 nm-thick stack of 5 nm HfO2-4 nm TiO2 bilayers (0.51 mole fraction HfO2) is sputter deposited on fused SiO2 and annealed in air at 1173 K for up to 192 h and then at 1273 K for up to 96 h. X-ray diffraction shows that hafnon crystallizes after 24 h at 1273 K. Micro-Raman spectroscopy/microscopy shows that hafnon crystallization is heterogeneous. No film-substrate reaction is observed for single layer HfO2 on SiO2annealed under similar conditions. We suggest the nanolaminate’s complex annealed microstructure provides fast diffusion paths that enable hafnon formation.

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Scitation: Addendum to “Phase selection and transition in Hf-rich hafnia-titania nanolaminates” (on SiO2) [J. Appl. Phys.109, 123523 (2011)]: Hafnon formation
http://aip.metastore.ingenta.com/content/aip/journal/jap/111/10/10.1063/1.4719968
10.1063/1.4719968
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