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Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment
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10.1063/1.4811540
/content/aip/journal/jap/113/23/10.1063/1.4811540
http://aip.metastore.ingenta.com/content/aip/journal/jap/113/23/10.1063/1.4811540
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Figures

Image of FIG. 1.
FIG. 1.

θ-2θ patters of the NiO/c-YSZ/Si heterostructures: (a) pristine sample, (b) laser annealed sample, and (c) high resolution θ-2θ scan of the pristine and laser treated samples.

Image of FIG. 2.
FIG. 2.

φ-Patterns acquired from NiO(200) reflection (2θ = 43.31°, ψ = 54.24°), c-YSZ(202) reflection (2θ = 50.37°, ψ = 45.00°), and Si(202) reflection (2θ = 47.57°, ψ = 45.00°).

Image of FIG. 3.
FIG. 3.

High resolution TEM micrographs showing a crystallographically continuous domain boundary in the NiO epilayer.

Image of FIG. 4.
FIG. 4.

Schematic illustration of the epitaxial relationship across the NiO/c-YSZ interface. NiO and c-YSZ lattices are represented in red and blue, respectively.

Image of FIG. 5.
FIG. 5.

High resolution TEM image of the interface between the NiO epilayer and the c-YSZ buffer.

Image of FIG. 6.
FIG. 6.

(a) Cross section bright field image and the SAED pattern taken from the laser annealed sample and (b) interface between the pristine and the laser treated regions. The SAED pattern belongs to Si[110], c-YSZ[110], and NiO zones.

Image of FIG. 7.
FIG. 7.

O(1s) core level binding energy in: (a) as-deposited and (b) laser annealed samples.

Image of FIG. 8.
FIG. 8.

Ni(2p) core level binding energy in: (a) as-deposited and (b) laser annealed samples.

Image of FIG. 9.
FIG. 9.

The effect of nanosecond laser annealing on the photocatalytic activity of NiO(111)/c-YSZ(001)/Si(001) heterostructures.

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/content/aip/journal/jap/113/23/10.1063/1.4811540
2013-06-21
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment
http://aip.metastore.ingenta.com/content/aip/journal/jap/113/23/10.1063/1.4811540
10.1063/1.4811540
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