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/content/aip/journal/jap/118/19/10.1063/1.4935087
2015-11-20
2016-12-09

Abstract

The high pressure and temperatureequation of state of cobalt metal in the face-centered cubic phase was measured up to 57 GPa and 2400 K using the laser heated diamond anvil cell in conjunction with synchrotron X-ray diffraction. The measured region is bisected by a ferromagnetic to paramagnetictransition across the Curie temperature necessitating use of an equation of state that incorporates a 2nd order phase transition within its formalism. A third order Birch-Murnaghan equation of state with a Mie-Grüneisen-Debye thermal correction and a Hillert-Jarl magnetic correction is employed to describe the data above and below the Curie temperature. We find best fit parameters of  = 6.753 (fixed) cm3/mol,  = 196 (3) GPa,  = 4.7 (2),  = 2.00 (11),  = 1.3 (5), and  = 385 K (fixed).

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