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H. Lüth, Solid Surfaces, Interfaces and Thin Films ( Springer-Verlag, 2010).
E. B. K. Jousten, in Handbook of Vacuum Technology, edited by K. Jousten ( Wiley-VCH, 2008).
P. F. Man and S. J. Pace, “ Electrospray deposition: Devices and methods thereof,” U.S. patent 8,007,871 B2 (NanoSelect, Inc., 2011), p. 23.
J. C. Swarbrick, J. B. Taylor, and J. N. O'Shea, “ Electrospray deposition in vacuum,” Appl. Surf. Sci. 252(15), 56225626 (2006).
C. Hamann et al., “ Ultrahigh vacuum deposition of organic molecules by electrospray ionization,” Rev. Sci. Instrum. 82(3), 033903 (2011).
S. K. Park et al., “ High mobility solution processed 6, 13-bis (triisopropyl-silylethynyl) pentacene organic thin film transistors,” Appl. Phys. Lett. 91(6), 063514 (2007).
W. Pisula et al., “ A zone-casting technique for device fabrication of field-effect transistors based on discotic hexa-peri-hexabenzocoronene,” Adv. Mater. 17(6), 684689 (2005).
M. Amati, M. K. Abyaneh, and L. Gregoratti, “ Dynamic high pressure: A novel approach toward near ambient pressure photoemission spectroscopy and spectromicroscopy,” J. Instrum. 8(5), T05001 (2013).
T. Kawai, H. Tanaka, and T. Nakagawa, “ Low dimensional self-organization of DNA-base molecules on Cu(111) surfaces,” Surf. Sci. 386, 124 (1997).
H. Tanaka and T. Kawai, “ Scanning tunneling microscopy imaging and manipulation of DNA oligomer adsorbed on Cu(111) surfaces by pulse injection method,” J. Vac. Sci. Technol., B 15(3), 602 (1997).
H. Tanaka et al., “ High-resolution scanning tunneling microscopy imaging of DNA molecules on Cu(111) surfaces,” Surf. Sci. 432(3), L611L616 (1999).
T. Kanno et al., “ Real space observation of double-helix DNA structure using a low temperature scanning tunneling microscopy,” Jpn. J. Appl. Phys., Part 2 38(6A), L606 (1999).
H. Kasai et al., “ STM observation of single molecular chains of pi conjugated polymers,” Chem. Lett. 31(7), 696697 (2002).
S. Keni-chi et al., “ A mandala-patterned bandanna-shaped porphyrin oligomer, C1244H1350N84Ni20O88, having a unique size and geometry,” Chem. Lett. 28(11), 11931194 (1999).
H. Tanaka and T. Kawai, “ Partial sequencing of a single DNA molecule with a scanning tunnelling microscope,” Nat. Nanotechnol. 4(8), 518522 (2009).
H. Tanaka and T. Kawai, “ Visualization of detailed structures within DNA,” Surf. Sci. 539(1–3), L531L536 (2003).
M. F. W. Nimmrich, Atomic-Scale Characterization of Diamond Surfaces and Fullerene Self-Assembly ( Johannes Gutenberg-Mainz, 2012), p. 165.
M. Yusuke et al., “ Fabrication of ionic liquid ultrathin film by sequential deposition,” Jpn. J. Appl. Phys., Part 1 53(5S1), 05FY01 (2014).
M. Manin et al., “ Deposition of MgO thin film by liquid pulsed injection MOCVD,” Surf. Coat. Technol. 200(5), 14241429 (2005).
M. Burriel et al., “ Growth kinetics, composition, and morphology of Co3O4 thin films prepared by pulsed liquid-injection MOCVD,” Chem. Vap. Deposition 11(2), 106111 (2005).
R. Bernard et al., “ Ultrahigh vacuum deposition of CdSe nanocrystals on surfaces by pulse injection,” J. Phys.: Condens. Matter 16(43), 7565 (2004).
A. Eisenstein et al., “ Pulsed-dosing controls self-assembly: 1-Bromopentane on Si(111)-7 × 7,” Chem. Phys. Lett. 527, 16 (2012).
T. Zambelli, Y. Boutayeb, F. Gayral, J. Lagoute et al., “ Deposition of large organic molecules in ultra-high vacuum: A comparison between thermal sublimation and pulse-injection,” Nanoscience 3(3), 12 (2004).
S. Ghosal, “ Electron spectroscopy of aqueous solution interfaces reveals surface enhancement of halides,” Science 307(5709), 563566 (2005).
L. Grill et al., “ Preparation of self-ordered molecular layers by pulse injection,” Surf. Sci. 600(11), L143L147 (2006).
G. Scoles, Atomic and Molecular Bean Methods ( Oxford University Press, Incorporated, 1988), Vol. 1.
J. M. Hollas, Jet Spectroscopy and Molecular Dynamics ( Springer, 1995).
P. J. Yunker et al., “ Suppression of the coffee-ring effect by shape-dependent capillary interactions,” Nature 476(7360), 308311 (2011).
R. D. Deegan et al., “ Capillary flow as the cause of ring stains from dried liquid drops,” Nature 389(6653), 827829 (1997).
J. F. Moulder et al., Handbook of X-Ray Photoelectron Spectroscopy ( Perkin Elmer Corporation, 1992).
C. Briones et al., “ Ordered self-assembled monolayers of peptide nucleic acids with DNA recognition capability,” Phys. Rev. Lett. 93(20), 208103 (2004).
A. Spitzer and H. Lüth, “ The adsorption of oxygen on copper surfaces: I. Cu (100) and Cu (110),” Surf. Sci. 118(1), 121135 (1982).
A. I. Stadnichenko, A. M. Sorokin, and A. I. Boronin, “ XPS, UPS, and STM studies of nanostructured CuO films,” J. Struct. Chem. 49(2), 341347 (2008).

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We have combined a fast-valve device with vacuum technology for implementing a new method that allows introducing liquid solutions in an ultra-high vacuum chamber in the form of very small droplets. This technical development allows the easy deposition of (bio) organic molecules or small nanoparticles on a surface in a fully process, avoiding possible contamination due to the handle of the material. Moreover, our experimental set-up is suitable for any liquid and does not require any voltage application as in electrospray. We can easily change the operating regime from liquid droplet injection to the formation of a highly dispersive jet of micro-droplets by exclusively adjusting external parameters. Due to the nature of the injection process, the operational protocol makes possible the deposition of delicate molecular species that cannot be thermally sublimated. In particular, we have used this system to study the deposition of adenosine triphosphate on Cu(110). The structure of the layer was analyzed by X-ray photoemission spectroscopy and the evolution of the signal from the deposited molecule with the number of injections indicates that the molecular coverage can be controlled with submonolayer precision.


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