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Approximate Emissivity Calculations for Polyatomic Molecules. I. CO2
1.(a) S. S. Penner, J. Appl. Phys. 21, 685 (1950);
1.(b) S. S. Penner, J. Appl. Mech. 18, 53 (1951);
1.(c) S. S. Penner and D. Weber, J. Appl. Phys. 22, 1164 (1951).
2.(a) Penner, Ostrander, and Tsien, J. Appl. Phys. 23, 256 (1952);
2.(b) S. S. Penner, J. Appl. Phys. 23, 825 (1952).
3.Holm, Weber, and Penner, J. Appl. Phys. 23, 1283 (1952).
4.W. H. McAdams, Heat Transmission (McGraw‐Hill Book Company, Inc., New York, 1942), Chapter III by H. C. Hottel.
5.A. M. Thorndike, J. Chem. Phys. 15, 868 (1947).
6.D. F. Eggers, Jr. and B. L. Crawford, Jr., J. Chem. Phys. 19, 1554 (1951).
7.Weber, Holm, and Penner, J. Chem. Phys. 20, 1820 (1952).
8.D. M. Dennison, Revs. Modern Phys. 3, 280 (1931).
9.D. M. Dennison, Revs. Modern Phys. 12, 175 (1940).
10.Slight corrections to the listed numerical values have beer, noted by W. S. Benedict and his collaborators. For the present purposes these corrections are negligibly small. Recent work on frequencies of lines belonging to is described in the following papers: Benedict, Herman, and Silverman, J. Chem. Phys. 19, 1325 (1951);
10.Taylor, Benedict, and Strong, Progress Report on “Infrared Spectra of and at 500 °C,” Contract Nonr 248‐01, The Johns Hopkins University, March, 1952.
11.The amplitude factors given in Eqs. (4) to (4g) are 4 times as large as those listed by Dennison (reference 8) because we are using a Fourier series in time of the form rather than .
12.B. L. Crawford, Jr. and H. L. Dinsmore, J. Chem. Phys. 18, 983, 1682 (1950).
13.Eggers and Crawford (reference 6) have shown how to relate for the matrix coefficients to the coefficients of Taylor series expansions of the potential energy and dipole moment about their respective equilibrium values.
14.G. Herzberg, Infrared and Raman Spectra of Polyatomic Molecules (D. Van Nostrand Company, Inc., New York, 1951), Table 56 on p. 274. Herzberg’s designations of band intensities as vs (very strong), s (strong), m (medium), w (weak), and vw (very weak) has been used in Figs. 1 to 3 to identify the approximate strengths of bands at room temperature.
15.Taylor, Benedict, and Strong, Progress Report on “Infrared Spectra of and at 500 °C,” Contract Nonr 248‐01, The Johns Hopkins University, Baltimore, March, 1952.
16.L. D. Kaplan, J. Chem. Phys. 18, 186 (1950).
17.E. Schrödinger, Ann. Physik 80, 483 (1926).
18.W. H. Shaffer, Revs. Modern Phys. 16, 245 (1944).
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