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Nonadiabaticity and intramolecular electronic energy transfer in the photodissociation of 1‐bromo‐3‐iodopropane at 222 nm
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41.Reference 22 noted the dependence of coupling on the orientation of the chromophores, and attempted to explain the lack of excitation transfer in by arguing that energy transfer would be carried by the Förster term and arguing from the dipole-dipole expression for Förster energy transfer that the probability of transfer in would be negligible. Reference 16 notes that in the formulation of this argument the Förster term was originally evaluated incorrectly and that the argument was not supported when the Förster term was correctly calculated. The dipole-dipole formulation of the Förster term, with its implicit assumption that the chromophores may be treated as well-separated dipoles, seems inapplicable to this system in any case.
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