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Statistical Mechanics of Cross‐Linked Polymer Networks II. Swelling
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5.While the theory appears to give remarkably good agreement with experiment at high polymer concentrations, we agree with Gee and Treloar that some improvement at low concentrations is desirable. The theory is notably unsatisfactory in very dilute solutions; see, P. J. Flory, J. Am. Chem. Soc. 65, 372 (1943). These matters have been discussed in detail elsewhere (paper presented before the Division of Physical and Inorganic Chemistry at the Pittsburgh Meeting of the American Chemical Society, Sept. 6, 1943).
6.This arbitrary definition of the segment size is of no consequence in the final results.
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