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Effects of equilibrium H-bond distance and angle changes on Raman intensities from water
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4.Absolute Raman intensities are defined here as those obtained under rigorously constant conditions of excitation intensity and detection geometry. Some workers, however, go further and calibrate the Raman intensities in terms of cm2/mol sr. This latter calibration has no advantage with regard to determining temperature dependences.
5.The excitation intensity was monitored and found to be constant to within 1%–3% over a 24 h period.
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