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Sum frequency vibrational spectroscopy of leucine molecules adsorbed at air–water interface
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12.In principle, the amplitudes of the two antisymmetric modes in the SSP spectra can also be used in the analysis. However, due to the close proximity of to these two modes, it is difficult to deduce their amplitudes from the spectra with good accuracy. In the SPS spectra, is weak and then the amplitudes of the antisymmetric modes can be reliably determined. In our analysis, we used the four amplitudes that were more reliably determined, two on the antisymmetric modes from the SPS spectra and two on the symmetric mode from the SPS and SSP spectra.
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