Background-subtracted Fourier transform infrared (FTIR) spectra of the OD stretch of HOD in in bulk water and in AOT reverse micelles.
Vibrational population relaxation of the OD stretch of HOD in in AOT reverse micelles (see text and Table I).
Orientational anisotropy decays of the OD stretch of HOD in in bulk water and in AOT reverse micelles and biexponential fits (see Table II). (a) Long time scale. (b) Expanded time scale. Note the differences in between the bulk water value and the reverse micelle values .
MD simulations of the orientational dynamics of water in AOT reverse micelles (Ref. 27) and triexponential fits (see Tables IV and V).
Vibrational excited state lifetime decay constant, values.
Anisotropy decay parameters.
Cone angles and diffusion constants.
Simulation orientational correlation function decay parameters.
Simulation cone angles and diffusion constants.
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