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Orientational dynamics of water confined on a nanometer length scale in reverse micelles
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10.1063/1.1883605
/content/aip/journal/jcp/122/17/10.1063/1.1883605
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/17/10.1063/1.1883605

Figures

Image of FIG. 1.
FIG. 1.

Background-subtracted Fourier transform infrared (FTIR) spectra of the OD stretch of HOD in in bulk water and in AOT reverse micelles.

Image of FIG. 2.
FIG. 2.

Vibrational population relaxation of the OD stretch of HOD in in AOT reverse micelles (see text and Table I).

Image of FIG. 3.
FIG. 3.

Orientational anisotropy decays of the OD stretch of HOD in in bulk water and in AOT reverse micelles and biexponential fits (see Table II). (a) Long time scale. (b) Expanded time scale. Note the differences in between the bulk water value and the reverse micelle values .

Image of FIG. 4.
FIG. 4.

MD simulations of the orientational dynamics of water in AOT reverse micelles (Ref. 27) and triexponential fits (see Tables IV and V).

Tables

Generic image for table
Table I.

Vibrational excited state lifetime decay constant, values.

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Table II.

Anisotropy decay parameters.

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Table III.

Cone angles and diffusion constants.

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Table IV.

Simulation orientational correlation function decay parameters.

Generic image for table
Table V.

Simulation cone angles and diffusion constants.

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/content/aip/journal/jcp/122/17/10.1063/1.1883605
2005-04-29
2014-04-25
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Orientational dynamics of water confined on a nanometer length scale in reverse micelles
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/17/10.1063/1.1883605
10.1063/1.1883605
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