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Dispersion of the Raman depolarization ratio of HDO in water and heavy water from , and from concentrated
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10.1063/1.1883626
/content/aip/journal/jcp/122/17/10.1063/1.1883626
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/17/10.1063/1.1883626
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Polarized, upper, and depolarized, lower, Raman spectra from in water at room temperature.

Image of FIG. 2.
FIG. 2.

Dispersion of , where is the depolarization ratio and . normalizes to unity at .

Image of FIG. 3.
FIG. 3.

Dispersion of the depolarization ratio for . , in water.

Image of FIG. 4.
FIG. 4.

Comparison of the depolarization ratios from binary and saturated ternary solutions at room temperature.

Image of FIG. 5.
FIG. 5.

Dispersion of the depolarization ratio for . , in heavy water.

Image of FIG. 6.
FIG. 6.

Low- and high-frequency regions of the depolarization ratio, same mol fraction as Fig. 5. The vertical scale of panel (a) of this figure begins at 1.5; not at zero.

Image of FIG. 7.
FIG. 7.

The ratio vs the Raman shift for dilute in heavy water as determined from the data of Murphy and Bernstein. refers to the isotropic polarizability and the anisotropic polarizability.

Image of FIG. 8.
FIG. 8.

Schematic diagram of bent H-bond.

Image of FIG. 9.
FIG. 9.

Calculated dispersion for the OH stretch of HDO in heavy water. Inset, see text.

Image of FIG. 10.
FIG. 10.

Depolarization ratio dispersion for pure water. –Murphy; circles–Walrafen, see Refs. 6 and 7.

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/content/aip/journal/jcp/122/17/10.1063/1.1883626
2005-04-29
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Dispersion of the Raman depolarization ratio of HDO in water and heavy water from 295to368K, and from concentrated NaClO4∕D2O∕H2O
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/17/10.1063/1.1883626
10.1063/1.1883626
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