Polarized, upper, and depolarized, lower, Raman spectra from in water at room temperature.
Dispersion of , where is the depolarization ratio and . normalizes to unity at .
Dispersion of the depolarization ratio for . , in water.
Comparison of the depolarization ratios from binary and saturated ternary solutions at room temperature.
Dispersion of the depolarization ratio for . , in heavy water.
Low- and high-frequency regions of the depolarization ratio, same mol fraction as Fig. 5. The vertical scale of panel (a) of this figure begins at 1.5; not at zero.
The ratio vs the Raman shift for dilute in heavy water as determined from the data of Murphy and Bernstein. refers to the isotropic polarizability and the anisotropic polarizability.
Schematic diagram of bent H-bond.
Calculated dispersion for the OH stretch of HDO in heavy water. Inset, see text.
Depolarization ratio dispersion for pure water. –Murphy; circles–Walrafen, see Refs. 6 and 7.
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