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Temperature effects for isothermal polymer crystallization kinetics
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10.1063/1.1924502
/content/aip/journal/jcp/122/24/10.1063/1.1924502
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/24/10.1063/1.1924502

Figures

Image of FIG. 1.
FIG. 1.

Time evolution of (a) number of macromolecules , (b) average cluster size , (c) nucleation rate , and (d) at , 0.972, 0.974, and 0.976 with parameters given in Table I.

Image of FIG. 2.
FIG. 2.

Effect of temperature dependence of interfacial energy with and other parameters given in Table I.

Image of FIG. 3.
FIG. 3.

Effect of activation energy with and other parameters given in Table I.

Image of FIG. 4.
FIG. 4.

Effect of phase transition enthalpy with and other parameters given in Table I.

Image of FIG. 5.
FIG. 5.

Effect of nucleation rate prefactor with and other parameters given in Table I.

Image of FIG. 6.
FIG. 6.

Effect of denucleation at different nucleation rates with and other parameters given in Table I. The dotted lines denote the moment solutions while the solid lines represent the numerical solutions.

Image of FIG. 7.
FIG. 7.

The effect of on the Avrami plots with at different nucleation rate prefactors: (a) , (b) , (c) , and (d) and other parameters given in Table I. The dotted lines denote the moment solutions while the solid lines represent the numerical solutions.

Image of FIG. 8.
FIG. 8.

The fit of distribution model to the experimental data for PBFP at four temperatures: (∎) , (●) , (▴) , (▾) , and other parameters given in Table I. The dotted lines denote the moment solutions while the solid lines represent the numerical solutions.

Image of FIG. 9.
FIG. 9.

The fit of distribution model with to the experimental data for PET at four temperatures: (∎) , (●) , (▴) , (▾) , with , and other parameters given in Table I.

Image of FIG. 10.
FIG. 10.

The fit of distribution model with to the experimental data for PEO at three temperatures: (∎) , (●) , (▴) , , and other parameters given in Table I.

Tables

Generic image for table
Table I.

Parameter values in figures (unless otherwise noted in captions).

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/content/aip/journal/jcp/122/24/10.1063/1.1924502
2005-06-29
2014-04-21
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Temperature effects for isothermal polymer crystallization kinetics
http://aip.metastore.ingenta.com/content/aip/journal/jcp/122/24/10.1063/1.1924502
10.1063/1.1924502
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