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The formation of from the reaction of with
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10.1063/1.2050648
/content/aip/journal/jcp/123/13/10.1063/1.2050648
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/13/10.1063/1.2050648

Figures

Image of FIG. 1.
FIG. 1.

Schematic diagram of the experimental apparatus.

Image of FIG. 2.
FIG. 2.

Section of the coincidence spectrum recorded following collisions of with at 7.1 eV. The spectrum clearly shows the two dissociative electron transfer reactions and the two bond-forming reactions that occur in this collision system [Eqs. (23)–(26)]. The horizontal line in the spectrum at the time of flight of is due to the contribution of false coincidences involving unreacted ions. See text for details.

Image of FIG. 3.
FIG. 3.

Plot of the intensity of reaction (25) in the coincidence pair spectrum against the intensity of reaction (23) as a function of the center-of-mass collision energy.

Image of FIG. 4.
FIG. 4.

Scattering diagrams for (a) and and (b) and N formed in reaction (25), recorded following collisions of with at 7.1 eV, with respect to the velocity of the center of mass. The spectrum was recorded under conditions which collect the full angular scattering. The arrow labeled , which is drawn from the origin of the diagram marked by a dot, represents the direction of the velocity of the center of mass. In this diagram is the radial coordinate and , the angle between and , is the angular coordinate. Since , the data for is plotted in the upper semicircle of (a) and the data for in the lower semicircle. Similarly, the data for is plotted in the upper semicircle of (b) and the data for N in the lower semicircle. See text for details.

Image of FIG. 5.
FIG. 5.

Internal frame scattering diagram showing the motion of and N formed in reaction (25), recorded following collisions of with at 7.1 eV, relative to that of . In this diagram is the radial coordinate and the angle between and is the angular coordinate. The data for is plotted in the upper semicircle of the figure and the data for N in the lower semicircle. See caption for Fig. 4 and text for details.

Image of FIG. 6.
FIG. 6.

Internal frame scattering diagram showing the motion of and formed in reaction (25), recorded following collisions of with at 7.1 eV, relative to that of N. In this diagram is the radial coordinate and , the angle between and , is the angular coordinate. The data for is plotted in the upper semicircle of the figure and the data for in the lower semicircle. See text for details.

Image of FIG. 7.
FIG. 7.

Internal frame scattering diagram showing the motion of and formed in reaction (26), recorded following collisions of with at 7.1 eV, relative to that of O. In this diagram is the radial coordinate and , the angle between and , is the angular coordinate. The data for is plotted in the upper semicircle of the figure and the data for in the lower semicircle. See text for details.

Tables

Generic image for table
Table I.

Geometric parameters of the “tetrahedral” singlet minima of determined by a optimization.

Generic image for table
Table II.

Geometric parameters of the “linear” triplet minima of determined by a optimization, with connectivity .

Generic image for table
Table III.

Relative energetics of the relevant reactant, product, and intermediate configurations for reaction (26).

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/content/aip/journal/jcp/123/13/10.1063/1.2050648
2005-10-06
2014-04-21
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: The formation of NO+ from the reaction of N22+ with O2
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/13/10.1063/1.2050648
10.1063/1.2050648
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