(a) Schema of the adiabatic potential-energy curves for the lowest electronic states of LiAr (Refs. 14 and 16) and (b) long-range behavior of the and states of isotopomer.
(a) The diagonal spin-orbit splitting of the state and (b) the off-diagonal spin-orbit coupling matrix elements between the and , states of LiAr.
(a) The ab initio angular coupling and (b) transition dipole moments between the , , and states of isotopomer.
Histograms of the deviations of the ICCA rovibronic term values from their experimental counterparts for (a) and (b) isotopomers. The histogram (c) was obtained by neglecting of the perturbations for the isotopomer. denotes the number of terms.
The resulting parameters of the empirical PEC for the state of ( and in , , and in angstrom, in , and in ). The value is referred to the ground ; level of the state. The estimated standard deviations are given in parenthesis while a strong correlation between the and parameters is observed.
The resulting parameters (in ) of the correction function for the state of (, , and in angstrom). The total empirical PEC for the state is available from EPAPS archive and website (Ref. 45).
The resulting parameters of the diagonal and off-diagonal spin-orbit coupling functions.
Equilibrium distance (angstrom), well depth , and dispersion coefficients and for the and states of LiAr.
Experimental (Ref. 14) and calculated spin-rotation splitting parameters (in ) for the ground state of the isotopomers.
Article metrics loading...
Full text loading...