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Cylinder-gyroid-lamella transitions in diblock copolymer solutions: A simulated annealing study
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10.1063/1.2137711
/content/aip/journal/jcp/123/23/10.1063/1.2137711
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/23/10.1063/1.2137711
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Schematics of the trial moves used in the simulated annealing. The solid circles represent monomers on the chain; open circles represent solvent molecules.

Image of FIG. 2.
FIG. 2.

The phase diagram for the in selective solvents for segments.

Image of FIG. 3.
FIG. 3.

The morphologies occurred in Fig. 2. They are formed with . (a) ; (b) ; (c) . (d) The calculated spherically averaged structure factor of the simulated G structure in (b). The calculated data (•) and the magnified version (◻) are indicated in the figure. The arrows indicated reflections correspond to the allowed ratios for the G structure of , , , , , , , , , , , , , , , , and (Ref. 35), where .

Image of FIG. 4.
FIG. 4.

Perforated layer structure formed with and : (a) all layers are shown; (b) only one layer is shown.

Image of FIG. 5.
FIG. 5.

The variation of the average contact number for the monomer with polymer concentration.

Image of FIG. 6.
FIG. 6.

The variation of the average contact number for the monomer with polymer concentration.

Image of FIG. 7.
FIG. 7.

The variation of the average contact number for each monomer with .

Image of FIG. 8.
FIG. 8.

The variation of the average contact number for each monomer with .

Image of FIG. 9.
FIG. 9.

The variation of the mean-square end-to-end distance of chain as a function with polymer concentration.

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/content/aip/journal/jcp/123/23/10.1063/1.2137711
2005-12-19
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Cylinder-gyroid-lamella transitions in diblock copolymer solutions: A simulated annealing study
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/23/10.1063/1.2137711
10.1063/1.2137711
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