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Experimental and theoretical study of the adsorption of fumaramide [2]rotaxane on Au(111) and Ag(111) surfaces
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10.1063/1.2137694
/content/aip/journal/jcp/123/24/10.1063/1.2137694
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/24/10.1063/1.2137694

Figures

Image of FIG. 1.
FIG. 1.

Schematic drawing showing the chemical structure of fumaramide [2]rotaxane.

Image of FIG. 2.
FIG. 2.

X-ray photoemission spectra of the C core levels for: a fumaramide [2]rotaxane (a) multilayer on Ag(111), (b) monolayer on Ag(111), and (c) monolayer on Au(111). Raw data (∎) and fit to the experimental data (—).

Image of FIG. 3.
FIG. 3.

X-ray photoemission spectra of the N core levels for: a fumaramide [2]rotaxane (a) multilayer on Ag(111), (b) monolayer on Ag(111), and (c) monolayer on Au(111). Raw data (∎) and fit to the experimental data (—).

Image of FIG. 4.
FIG. 4.

X-ray photoemission spectra of the O core levels for: a fumaramide [2]rotaxane (a) multilayer on Ag(111), (b) monolayer on Ag(111), and (c) monolayer on Au(111). Raw data (∎) and fit to the experimental data (—).

Image of FIG. 5.
FIG. 5.

The average structure of fumaramide [2]rotaxane on (a) Ag(111) and (b) Au(111). The structures were obtained by averaging atom locations of a molecular-dynamics run at . The average structure from the MD runs resembles a collapsed letter X. Color code: , , , and .

Image of FIG. 6.
FIG. 6.

HREELS spectra collected in specular scattering geometry at a primary beam energy of from fumaramide [2]rotaxane monolayer (a) and multilayer (b) adsorbed on Au(111) at . . Inset: solid-state infrared spectrum of fumaramide [2]rotaxane.

Tables

Generic image for table
Table I.

Comparison between the experimental atomic percentages derived from the photoemission peak areas of fumaramide [2]rotaxane and the theoretical values calculated from the stoichiometry of the rotaxane.

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/content/aip/journal/jcp/123/24/10.1063/1.2137694
2005-12-30
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Experimental and theoretical study of the adsorption of fumaramide [2]rotaxane on Au(111) and Ag(111) surfaces
http://aip.metastore.ingenta.com/content/aip/journal/jcp/123/24/10.1063/1.2137694
10.1063/1.2137694
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