1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Anomalous temperature-isotope dependence in proton-coupled electron transfer
Rent:
Rent this article for
USD
10.1063/1.2188395
/content/aip/journal/jcp/124/16/10.1063/1.2188395
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/16/10.1063/1.2188395
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Theoretical curves of the rate in vs in K for the zeroth order term of Eq. (9) (long dashing), the zeroth plus first order term of Eq. (9) (intermediate dashing), and the sum of all orders (short dashings). The following parameter values were used: of proton, , , , , , , and .

Image of FIG. 2.
FIG. 2.

Theoretical curves depicting -isotope dependence for ET rates with protons (dashed line) and deuterons (solid line) along the H-bonding interface. The axes are the same as in (Fig. 1). The following parameter values were used: Isotope effect used is the usual , of proton, , , , , , , and .

Image of FIG. 3.
FIG. 3.

Theoretical curves depicting -isotope dependence for ET rates with protons (dashed line) and deuterons (solid line) along the H-bonding interface. The axes are the same as in (Fig. 1). The following parameter values were used: Isotope effect used is the usual , of proton, , , , , , , and .

Image of FIG. 4.
FIG. 4.

Theoretical and experimental curves (with error bars) depicting -isotope dependence for ET assisted by protons, dashed line and triangles, respectively, and deuterons, solid line and squares, respectively. The axes are the same as in (Fig. 1). The following parameter values were used: Isotope effect used is the usual , of proton, , , , , , , and .

Loading

Article metrics loading...

/content/aip/journal/jcp/124/16/10.1063/1.2188395
2006-04-25
2014-04-20
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Anomalous temperature-isotope dependence in proton-coupled electron transfer
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/16/10.1063/1.2188395
10.1063/1.2188395
SEARCH_EXPAND_ITEM