1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Selective and reversible control of a chemical reaction with narrow-band infrared radiation: radical in solid xenon
Rent:
Rent this article for
USD
10.1063/1.2201445
/content/aip/journal/jcp/124/18/10.1063/1.2201445
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/18/10.1063/1.2201445
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

FTIR spectra of noble-gas molecules prepared from acetylene in solid Xe. (a) Spectrum of the photolysed and thermally annealed solid mixture. (b) Difference spectrum showing the result of irradiation of the photolysed and thermally annealed sample at . The spectra were measured with a Nicolet 60 SX FTIR spectrometer (resolution of ) at .

Image of FIG. 2.
FIG. 2.

Photodecomposition spectrum of and in solid Xe at . With a pulse energy density of , 200 pulses at decomposes about a half of radicals, which estimates photodecomposition cross-section of .

Image of FIG. 3.
FIG. 3.

Dark-recovery time of and as a function of 1/T. In the beginning, the molecules were partially decomposed by IR light. The recovery time was found by fitting the kinetics data with a single exponent.

Image of FIG. 4.
FIG. 4.

Recovery profiles of and (symbols) and FTIR spectrum of the first stretching overtone of . The Burleigh WA-4500 wavemeter provided the OPO radiation frequency with absolute accuracy better than , and the fine shift of the frequency scale is provided by the correction obtained in Ref. 24.

Loading

Article metrics loading...

/content/aip/journal/jcp/124/18/10.1063/1.2201445
2006-05-09
2014-04-18
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Selective and reversible control of a chemical reaction with narrow-band infrared radiation: HXeCC radical in solid xenon
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/18/10.1063/1.2201445
10.1063/1.2201445
SEARCH_EXPAND_ITEM