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Geometric phase effects in the coherent control of the branching ratio of photodissociation products of phenol
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10.1063/1.2203611
/content/aip/journal/jcp/124/22/10.1063/1.2203611
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/22/10.1063/1.2203611
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Adiabatic potential functions along the OH stretching coordinate for planar phenol . The adiabatic electronic states are referred to as the (solid line), (dotted line), and (dashed line) states. Parameters are from Ref. 29.

Image of FIG. 2.
FIG. 2.

(a) Two-dimensional, three-electronic-state model potential of phenol. Conical intersections appear at and , where denotes the OH bond length (CCOH dihedral angle). (b) Transition dipole moment function associated with the transition in the diabatic representation. Parameters are from Ref. 29.

Image of FIG. 3.
FIG. 3.

(a) Optimal control pulse that enhances the dissociation channel. (b) Dissociation probabilities associated with the product (dotted line) and the product (solid line). The dashed line shows the time-dependent population in the diabatic state.

Image of FIG. 4.
FIG. 4.

(a) Optimal control pulse that enhances the dissociation channel. (b) Dissociation probabilities associated with the product (dotted line) and the product (solid line). The dashed line shows the time-dependent population in the diabatic state.

Image of FIG. 5.
FIG. 5.

Cuts of the probability density on the adiabatic PES along the CCOH dihedral angle for various OH bond lengths at . The solid (dotted) line represents those cuts generated by the dissociation pulse. In each figure, the probability densities are plotted in the range . Vertical lines serve as a guide for the eye.

Image of FIG. 6.
FIG. 6.

Cuts of the probability density on the adiabatic PES along the CCOH dihedral angle for various OH bond lengths at . The solid (dotted) line represents those cuts generated by the dissociation pulse. In each figure, the probability densities are plotted in the range . Vertical lines serve as a guide for the eye.

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/content/aip/journal/jcp/124/22/10.1063/1.2203611
2006-06-13
2014-04-24
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Geometric phase effects in the coherent control of the branching ratio of photodissociation products of phenol
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/22/10.1063/1.2203611
10.1063/1.2203611
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