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Effects of conjugation length, electron donor and acceptor strengths on two-photon absorption cross sections of asymmetric zinc-porphyrin derivatives
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10.1063/1.2178790
/content/aip/journal/jcp/124/9/10.1063/1.2178790
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/9/10.1063/1.2178790

Figures

Image of FIG. 1.
FIG. 1.

Molecular structures of Zn-pophyrin derivatives.

Image of FIG. 2.
FIG. 2.

Electron distributions of the HOMO (left column) and the LUMO (right column) of all Zn-porphyrin derivatives. (A) DP-ZnP; (B) DP-ZnP-DA; (C) DP-ZnP-TDA; (D) DP-ZnP-2TDA; (E) DP-ZnP-TDAs; and (F) DP-ZnP-2TDAs.

Tables

Generic image for table
Table I.

Calculated one-photon absorption properties of the three low-lying singlet excited states at the level.

Generic image for table
Table II.

Absorption wavelengths ( and in micrometer), the transition dipole moment to the CT state , the dipole moments of the ground , and the CT states of the Zn-porphyrin derivatives calculated at the . The TPA cross section ( in GM) is calculated using the two-states model. All dipole moments are in the unit of Debye.

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/content/aip/journal/jcp/124/9/10.1063/1.2178790
2006-03-07
2014-04-23
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Effects of conjugation length, electron donor and acceptor strengths on two-photon absorption cross sections of asymmetric zinc-porphyrin derivatives
http://aip.metastore.ingenta.com/content/aip/journal/jcp/124/9/10.1063/1.2178790
10.1063/1.2178790
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