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Radical SBr: A challenge to spectroscopists?
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10.1063/1.2353827
/content/aip/journal/jcp/125/11/10.1063/1.2353827
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/11/10.1063/1.2353827

Figures

Image of FIG. 1.
FIG. 1.

Potential energy curves for the doublet states and the lowest-lying quartet state of the species SBr.

Image of FIG. 2.
FIG. 2.

Potential energy curves for the bound doublet states and the lowest-lying quartet state of the species SBr showing vibrational states and the transitions likely to be most intense.

Image of FIG. 3.
FIG. 3.

Spin-orbit coupling constants for the states of the species SBr.

Image of FIG. 4.
FIG. 4.

Dipole moment and transition dipole moment functions for the bound doublet states of the species SBr.

Tables

Generic image for table
Table I.

Vibrational level spacings (in ), rotational constants (in ), vibrationally averaged dipole moments (in ), and vibrationally averaged spin-orbit constants (in ) for states of SBr. For the Rydberg states are listed.

Generic image for table
Table II.

Spectroscopic constants for the and states of ; with the exception of , given in Å , all constants are given in .

Generic image for table
Table III.

Dipole moment absorption matrix elements (in ) in upper right and vibrationally averaged dipole moment matrix elements on the diagonal. Einstein spontaneous emission coefficients (in ) in lower left, and radiative lifetimes (in ms) for the bands of SBr.

Generic image for table
Table IV.

Radiative transition probabilities for emission as given by the Einstein coefficients (in ) and Franck-Condon factors, in parentheses, for the system of SBr, and upper bounds for the radiative lifetimes (in ns) for the states.

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/content/aip/journal/jcp/125/11/10.1063/1.2353827
2006-09-20
2014-04-23
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Scitation: Radical SBr: A challenge to spectroscopists?
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/11/10.1063/1.2353827
10.1063/1.2353827
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