1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Rotationally resolved reactive scattering: Imaging detailed reaction dynamics
Rent:
Rent this article for
USD
10.1063/1.2202827
/content/aip/journal/jcp/125/13/10.1063/1.2202827
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/13/10.1063/1.2202827

Figures

Image of FIG. 1.
FIG. 1.

Schematic diagram of the experimental apparatus: (a) Detail of the configuration of the crossed molecular beam setup. (b) Dc slice imaging detection scheme.

Image of FIG. 2.
FIG. 2.

Raw images of HCl (, ) at a collision energy of . The Newton diagram is imposed on the image of .

Image of FIG. 3.
FIG. 3.

Total angular distribution for HCl (, ) at the collision energy of .

Image of FIG. 4.
FIG. 4.

Translational energy distribution for HCl (, ) at a collision energy of . Solid line: total (10°–170°); dash line: forward (10°–60°); dotted line: sideways (60°–120°); dot-dashed line: backward (120°–170°). Arrows mark the translational energy limits.

Image of FIG. 5.
FIG. 5.

Translational energy distribution for HCl (, ) at the collision energy of . Solid line: Experimental result at backward direction (140°–170°). Dotted, dashed, and dot-dashed lines: Gaussian fitting results.

Image of FIG. 6.
FIG. 6.

(A)–(D) are the raw images of HCl (, ) at the collision energy of 3.2, 5.2, 6.7, and , respectively.

Image of FIG. 7.
FIG. 7.

(A)–(D) are the total angular distribution for HCl (, ) at the collision energy of 3.2, 5.2, 6.7, and , respectively.

Image of FIG. 8.
FIG. 8.

Translational energy distribution for HCl (, ) at different collision energies. (A)–(D) are collision energies of 3.2, 5.2, 6.7, and , respectively. Solid line: total (10°–170°); dashed line: forward (10°–60°); dotted line: sideways, (60°–120°); dot-dashed line: backward (120°–170°). Arrows mark the translational energy limits.

Image of FIG. 9.
FIG. 9.

Plot of average translational energy release vs collision energy for the forward scattered products for HCl , ).

Tables

Generic image for table
Table I.

Collision energy dependence: The fraction of the HCl rotational energy, the average translational energy, and the fraction of the energy deposited to ethyl radical internal excitation.

Generic image for table
Table II.

Contribution of slow component for HCl (, ) at different collision energies.

Loading

Article metrics loading...

/content/aip/journal/jcp/125/13/10.1063/1.2202827
2006-10-02
2014-04-18
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Rotationally resolved reactive scattering: Imaging detailed Cl+C2H6 reaction dynamics
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/13/10.1063/1.2202827
10.1063/1.2202827
SEARCH_EXPAND_ITEM