Absorption spectrum obtained from the irradiation of at , total pressure of diluent, and after photolysis.
A typical decay time profile of the absorption intensity of at at and total pressure of diluent. The inset shows the semilogarithm plots. . The solid line is a simulation result. See text for details.
Photolysis laser intensity dependence of the absorption of at and total pressure of diluent. and after photolysis.
Absorption intensities of at and after photolysis as a function of at and total pressure of diluent. The solid curve is a best fit of Eq. (6). Squares are the results of simulation for reactions (1a), (1b), and (2). See text for details.
Pressure effect of on formation of at and after photolysis. Concentration of is . The solid curves are fitting results with (thick) and (thin) for the linear structure. (dot) and (dash) for the bent structure. See text for details of simulation.
Temperature dependence of the relative absorption intensities at 1160, 1200, and , normalized to the absorption intensity at . total pressure of diluent. .
Decay profiles of with of (circle) or without (square) at and total pressure of diluent. The concentration of was .
Temperature dependence of the equilibrium constants ( in ) calculated at the and levels of theory.
Relative buffer gas effects on the absorption intensity of at and .
Optimized parameters of calculated at the MP4SDQ/6–311 level. Bond lengths and angles are in angstroms and in degrees, respectively.
Harmonic vibrational frequencies of (in ) and zero-point energies (ZPEs in kcal/mol) calculated at the level.
Reactions used for simulations at and total pressure of diluent.
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