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Electronic spectroscopy of complexes via the and Rydberg states
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10.1063/1.2348873
/content/aip/journal/jcp/125/14/10.1063/1.2348873
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/14/10.1063/1.2348873
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

REMPI spectra for the complex series. Note that for the NO–Ar and spectra shown here, the laser powers employed are in excess of the optimum, so that fragmentation from larger species can be seen to make minor contributions to the spectra. In addition, the and 2 spectra were recorded simultaneously, and consequently under identical conditions.

Image of FIG. 2.
FIG. 2.

REMPI spectra for NO–Ne and .

Image of FIG. 3.
FIG. 3.

Close-up of the band for NO–Ne and . The spectrum is shifted to the blue to facilitate comparison of the rovibrational structure.

Image of FIG. 4.
FIG. 4.

Two views of the optimized geometry for the “cross” structure of . The structure shown is for , with the one for looking very similar.

Image of FIG. 5.
FIG. 5.

Close-up of the band for NO–Ar and . The spectrum is shifted to the blue to facilitate comparison of the rovibrational structure.

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/content/aip/journal/jcp/125/14/10.1063/1.2348873
2006-10-13
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Electronic spectroscopy of NO–(Rg)x complexes (Rg=Ne,Ar) via the 4s and 3d Rydberg states
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/14/10.1063/1.2348873
10.1063/1.2348873
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