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Testing one component plasma models on colloidal overcharging phenomena
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10.1063/1.2357945
/content/aip/journal/jcp/125/14/10.1063/1.2357945
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/14/10.1063/1.2357945
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

(Color online) Distribution functions for ions vs the distance from the charged surface (normalized by the multivalent counterion diameter, ) for , , and . Squares, triangles and circles stand for multivalent counterions, monovalent counterions, and coions, respectively. Solid and open symbols denote the runs with 78 and 148 particles, respectively, in the simulation cell.

Image of FIG. 2.
FIG. 2.

(Color online) MC inversion ratio [calculated from Eq. (13) with ] as a function of the salt concentration for and (squares), 4 (circles), and 5 (triangles). Lines stand for the predictions of the SCL model by Perel and Shklovskii [Eq. (1)] for (solid), 4 (dashed), and 5 (dotted).

Image of FIG. 3.
FIG. 3.

Line inversion for . Squares stand for the MC simulation results, whereas the solid line denotes the prediction obtained from Eq. (1).

Image of FIG. 4.
FIG. 4.

(Color online) MC inversion ratio [calculated from Eq. (13) with ] as a function of the salt concentration for and (squares), 4 (circles), and 5 (triangles). Lines stand for the predictions of the OCP model by Levin [Eq. (6)] for (solid), 4 (dashed), and 5 (dotted).

Image of FIG. 5.
FIG. 5.

(Color online) MC inversion ratio [calculated from Eq. (13) with ] as a function of the 1:1 salt concentration for , , and (squares), 4 (circles), and 5 (triangles). Lines stand for the predictions of the OCP model by Levin [Eq. (6)] for (solid), 4 (dashed), and 5 (dotted).

Image of FIG. 6.
FIG. 6.

(Color online) MC inversion ratio [calculated from Eq. (13) with ] as a function of the 1:1 salt concentration for , , and (squares symbols). Lines stand for the predictions of the OCP model by Pianegonda et al. for and (solid line) and (dashed line).

Image of FIG. 7.
FIG. 7.

(Color online) MC inversion ratio [calculated from Eq. (13) with ] as a function of the parameter , which is proportional to the 1:1 salt concentration [see Eq. (5)], for , , and (circles) and 5 (triangles). The line stands for the predictions of the SCL model by Shklovskii and co-workers (Ref. 31).

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/content/aip/journal/jcp/125/14/10.1063/1.2357945
2006-10-12
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Testing one component plasma models on colloidal overcharging phenomena
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/14/10.1063/1.2357945
10.1063/1.2357945
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