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Probing the electronic properties of dichromium oxide clusters using photoelectron spectroscopy
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10.1063/1.2360531
/content/aip/journal/jcp/125/16/10.1063/1.2360531
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/16/10.1063/1.2360531

Figures

Image of FIG. 1.
FIG. 1.

Photoelectron spectra of at (a) , (b) , (c) , and (d) .

Image of FIG. 2.
FIG. 2.

Photoelectron spectra of at (a) 532, (b) 355, (c) 266, and (d) . The vertical bars represent the resolved vibrational structures.

Image of FIG. 3.
FIG. 3.

Photoelectron spectra of at (a) 532, (b) 355, (c) 266, and (d) . The inset in (a) shows the fine features within band .

Image of FIG. 4.
FIG. 4.

photoelectron spectra of under hot source conditions by using 0.5% seeded He carrier gas. Note the relative intensity of band increased markedly relative to Fig. 3(d), indicating contributions from a low-lying isomer.

Image of FIG. 5.
FIG. 5.

Photoelectron spectra of at (a) 355, (b) 266, and (c) . The vertical bars represent the resolved vibrational structures. “HB” stands for a hot band transition.

Image of FIG. 6.
FIG. 6.

Photoelectron spectra of at (a) 266 and (b) . The vertical bars represent the resolved vibrational structures.

Image of FIG. 7.
FIG. 7.

Photoelectron spectra of at (a) 266 and (b) . The vertical bars represent the resolved vibrational structures.

Image of FIG. 8.
FIG. 8.

photoelectron spectra of under hot source conditions by using 0.5% seeded He carrier gas. Note the relative intensities of bands and were significantly enhanced relative to Fig. 7(b), indicating the coexistence of two isomers in the cluster beam.

Image of FIG. 9.
FIG. 9.

Comparison of the photoelectron spectra of . denotes photodetachment transitions from Cr -derived orbitals and denotes those from O -derived orbitals.

Tables

Generic image for table
Table I.

Observed adiabatic and vertical detachment energies and vibrational frequencies from the photoelectron spectra of .

Generic image for table
Table II.

Comparison of the observed detachment transitions with previous DFT calculations from Ref. 10. All energies are in eV.

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/content/aip/journal/jcp/125/16/10.1063/1.2360531
2006-10-25
2014-04-21
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Probing the electronic properties of dichromium oxide clusters Cr2On−(n=1–7) using photoelectron spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/16/10.1063/1.2360531
10.1063/1.2360531
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