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Helium clusters seeded with CO molecules: New results for and the approach to the nanodroplet limit
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10.1063/1.2363196
/content/aip/journal/jcp/125/16/10.1063/1.2363196
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/16/10.1063/1.2363196

Figures

Image of FIG. 1.
FIG. 1.

Observed spectra of isotopic clusters in the region of the -type series. Numbers in circles are the assigned values of cluster size . The assignments 5a for and and 6a for are tentative ones made here in retrospect.

Image of FIG. 2.
FIG. 2.

Observed spectrum of the -type series for clusters. Numbers in circles are the “conventional” assigned values of cluster size .

Image of FIG. 3.
FIG. 3.

Plot of the -type series line positions for clusters. The large square points indicate the conventional assignment, and the smaller circles indicate the alternate assignment D (Table III).

Image of FIG. 4.
FIG. 4.

Spectra of -type transitions for larger (upper panel) and (lower panel) clusters. In each panel, the traces are stacked in order of increasing clustering, achieved by higher backing pressure and lower nozzle temperature. Numbers in circles are the conventional assigned values of cluster size .

Image of FIG. 5.
FIG. 5.

Spectra of -type transitions for even larger clusters. Traces are stacked in order of increasing clustering. Numbers in circles are the conventional assigned values of cluster size , but for these are only very approximate.

Image of FIG. 6.
FIG. 6.

Isotope effects in the -type series of clusters. The known CO monomer band origin for the particular isotope is first subtraced from each line position. The differences between these values for the substituted isotope and the normal one are then plotted. Note that most shifts lie very close to the sum of the respective and shifts.

Image of FIG. 7.
FIG. 7.

Isotope effects in the -type series of clusters. The known CO monomer band origin for the particular isotope is first subtraced from each line position. The differences between these values for the substituted isotope and the normal one are then plotted. Note that most shifts lie very close to the sum of the respective and shifts. Observed (Ref. 22) values for CO isotopes in helium nanodroplets are shown at the top of the figure.

Tables

Generic image for table
Table I.

Observed positions of transitions of clusters, with “conventional” cluster size numbering (in ).

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Table II.

Observed -type line positions for larger clusters, with conventional cluster size numbering (in ).

Generic image for table
Table III.

Alternate assignments for -type transitions of clusters (in ).

Generic image for table
Table IV.

Attempt to extract vibrational and rotational contributions to the -type series line positions from an isotope shift model (see text).

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/content/aip/journal/jcp/125/16/10.1063/1.2363196
2006-10-27
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Helium clusters seeded with CO molecules: New results for HeN–C1813O and the approach to the nanodroplet limit
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/16/10.1063/1.2363196
10.1063/1.2363196
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