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Equilibrium adsorption on single and aggregated nanospheres
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10.1063/1.2375092
Chu Nie1,a) and W. H. Marlow1,b)
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Affiliations:
1 Department of Nuclear Engineering, Texas A&M University, College Station, Texas 77843
a) Electronic mail: niechu@hotmail.com
b) Electronic mail: w-marlow@tamu.edu
J. Chem. Phys. 125, 174702 (2006)
/content/aip/journal/jcp/125/17/10.1063/1.2375092
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/17/10.1063/1.2375092
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## Figures

FIG. 1.

Density obtained for argon adsorption on a planar substrate at . Profiles are for densities of bulk fluid , 0.1, 0.15, 0.20, 0.25, 0.30, 0.32, and 0.348 79, where and .

FIG. 2.

Adsorption excess for argon adsorption on planar and spherical substrates with radii , , , , and at , with bulk densities from to for the spherical substrate and to for the planar case, where and .

FIG. 3.

Adsorption excess for argon adsorption on planar and spherical substrates with radii , , , , and at , with bulk densities from to for the spherical substrate and to for the planar case, where and .

FIG. 4.

Adsorption excess for argon adsorption on planar and spherical substrates with radii , , , , and at , with bulk densities from to for the spherical substrate and to for the planar case, where and .

FIG. 5.

Adsorption excess for argon adsorption on planar and spherical substrates with radii , , , , and at , with bulk densities , 0.01, 0.015, 0.020, 0.025, 0.030, 0.032, and 0.034 879 for the spherical substrate and , 0.01, 0.015, 0.020, 0.025, 0.030, and 0.032 for the planar case, where and .

FIG. 6.

Comparison of the density profiles for one sphere and two sphere cases at and bulk density is the coexistence density of gas phase. The density profile for two sphere case is plotted along the symmetry axial from the contacting point of two identical spheres.

FIG. 7.

Adsorption excess for argon adsorption on one and two contacting spherical substrates with radius , at , with bulk density from to , where and .

FIG. 8.

Adsorption excess for argon adsorption on one and two contacting spherical substrates with radius , at , with bulk density from to where and .

FIG. 9.

Adsorption excess for argon adsorption on one and two contacting spherical substrates with radius , at , with bulk density from to , where and .

/content/aip/journal/jcp/125/17/10.1063/1.2375092
2006-11-02
2014-04-19

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