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Infrared spectra of the complexes in argon matrices
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10.1063/1.2214716
/content/aip/journal/jcp/125/3/10.1063/1.2214716
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/3/10.1063/1.2214716

Figures

Image of FIG. 1.
FIG. 1.

Infrared absorption spectra recorded with resolution are reproduced in the OH stretching regions of isolated in argon matrices: (a) , (b) , (c) , and (d) . The complex is indicated by 1:1, and the complexes are marked by the asterisk.

Image of FIG. 2.
FIG. 2.

Infrared absorption spectra recorded with resolution are reproduced in the OH stretching regions of isolated in argon matrices: (a) and (b) . The labels indicated by are assigned to the complex.

Image of FIG. 3.
FIG. 3.

Infrared absorption spectra recorded with resolution are reproduced in the OH bending region of isolated in argon matrices: (a) , (b) , (c) , and (d) . The label indicated by 1:1 is assigned to the complex.

Image of FIG. 4.
FIG. 4.

Infrared absorption spectra recorded with resolution are reproduced in the SO stretching regions of isolated in argon matrices: (a) , (b) , and (c) . The labels indicate the assignment: M, monomer in the stable site; , monomer in the metastable site; D, dimer, m, monomer in the stable site; ; monomer in the metastable site; d, dimer; , complex.

Image of FIG. 5.
FIG. 5.

Optimized structures of , , , and with are shown schematically. The bond lengths and distances between atoms are in angstroms and the bond angles in degrees.

Tables

Generic image for table
Table I.

Observed and calculated frequencies , frequency shifts , and calculated intensities (km/mol) (intensities are given in parentheses) for the complex. The values of the monomers are given for comparison.

Generic image for table
Table II.

Observed and calculated frequencies , frequency shifts (shifts relative to the monomer values; in the case of the free and bonded OH stretching modes, the shifts were measured with respect to the and values respectively), and calculated intensities (km/mol) (intensities are given in parentheses) for the complex.

Generic image for table
Table III.

Observed and calculated frequencies , frequency shifts (shifts relative to the monomer values; in the case of the free and bonded OH stretching modes, the shifts were measured with respect to the and values, respectively), and calculated intensities (km/mol) (intensities are given in parentheses) for the complex.

Generic image for table
Table IV.

Observed and calculated frequency shifts for the complexes with respect to the frequency of the 1:1 complex.

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/content/aip/journal/jcp/125/3/10.1063/1.2214716
2006-07-20
2014-04-20
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Infrared spectra of the (H2O)n–SO2 complexes in argon matrices
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/3/10.1063/1.2214716
10.1063/1.2214716
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