1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Rydberg states of small clusters
Rent:
Rent this article for
USD
10.1063/1.2229210
/content/aip/journal/jcp/125/8/10.1063/1.2229210
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/8/10.1063/1.2229210

Figures

Image of FIG. 1.
FIG. 1.

Lowest energy structures and orbital contour plots of clusters .

Image of FIG. 2.
FIG. 2.

Lowest energy structures of , , and clusters (left: , center: , and right: ions) in the size range .

Image of FIG. 3.
FIG. 3.

Orbital contour plots for electronically excited clusters in (left) and (right) states for selected sizes (up) and (bottom).

Image of FIG. 4.
FIG. 4.

energy contributions for and excited states as functions of the ArNaAr angle at . Energies in and angles in degrees. Full line: total energy; dashed line: electronic contribution, and dotted line: contribution. The reference energy is the total energy at .

Image of FIG. 5.
FIG. 5.

energy contributions for and excited states as functions of the pyramidalization angle (the angle between the pyramid axis and one edge) at . Energies in and angles in degrees. Full line: total energy, dashed line: electronic contribution, and dotted line: contribution. The reference energy is the total energy at .

Image of FIG. 6.
FIG. 6.

Lowest energy structures of , , and clusters (left: , center: , and right: ions) in the size range .

Image of FIG. 7.
FIG. 7.

Size dependence of the energies of excited states of clusters. Squares: energies of optimized ground state clusters. Triangles: energies of optimized ionized clusters. Dots: excited energies of isomers actually optimized on their own potential energy surface (respectively, , , and ). Full lines: excited states energies calculated at the geometries of the positive ions. Dashed lines: excited states energies calculated at the geometries of the ground states neutrals. The zero energy is that of atomic .

Tables

Generic image for table
Table I.

Averaged nearest-neighbor NaAr distance (in borhs), principal quantum number , and dissociation energies and (in eV) for , , and clusters (see definitions in text).

Generic image for table
Table II.

Absorption and emission wavelengths for and states of clusters, determined from vertical transitions energies at the ground state geometries for and at the exciplex geometries for .

Loading

Article metrics loading...

/content/aip/journal/jcp/125/8/10.1063/1.2229210
2006-08-29
2014-04-24
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Rydberg states of small NaArn* clusters
http://aip.metastore.ingenta.com/content/aip/journal/jcp/125/8/10.1063/1.2229210
10.1063/1.2229210
SEARCH_EXPAND_ITEM