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Difference spectra of the doped solid hydrogens generated from spectra acquired before and after photolysis; Bottom, middle, and top respectively correspond to solid , , and . A 25 point Savitsky-Golay smooth and baseline correction were applied to the spectra. The sharp transition at of solid (bottom trace) has been artificially suppressed to highlight the Cl SO transitions.
Schematic diagram of the SO splitting in the gas-phase relative to that in solid . The Dirac electron cloud is shown in the ground and excited SO states surrounded by the first solvation shell of molecules.
Difference spectrum of doped solid generated from spectra acquired before and after UV photolysis showing the ZP SO transition. The smooth solid curve is the fitted Lorentzian lineshape.
Transition wavenumbers of absorptions involving the Cl SO transition in solid , , and . (uncertainties are estimated), side band. Resolved maxima reported.
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