(a) LIF excitation spectrum of 1-aminoindan, and UV-UV hole-burning spectra obtained by probing the bands at (b) and (c) . The dotted lines indicate the corresponding vibronic transitions in the spectra. The fluorescence dip in the spectra (b) and (c) originates from conformers and , respectively. See the text for details.
(Color online) Fully optimized structures of six conformers for 1-aminoindan calculated at the B3LYP/cc-pVTZ level.
SVLF spectra following excitation of the bands at (a) , (b) , and (c) for conformer .
SVLF spectra following excitation of the bands at (a) and (b) for conformer .
SVLF spectra following excitation of the bands at (a) for conformer and (b) for conformer .
Frequencies and assignments for the transition of 1-aminoindan.
Calculated energies relative to the most stable conformer I.
Observed and calculated vibrational frequencies at the B3LYP/cc-pVTZ level and their assignments for conformers and .
Fluorescene lifetime on the single vibronic level of 1-aminoindan and indan.
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