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Low-frequency vibrations specific for conformers of 1-aminoindan studied by UV-UV hole-burning spectroscopy
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10.1063/1.2736687
/content/aip/journal/jcp/126/21/10.1063/1.2736687
http://aip.metastore.ingenta.com/content/aip/journal/jcp/126/21/10.1063/1.2736687

Figures

Image of FIG. 1.
FIG. 1.

(a) LIF excitation spectrum of 1-aminoindan, and UV-UV hole-burning spectra obtained by probing the bands at (b) and (c) . The dotted lines indicate the corresponding vibronic transitions in the spectra. The fluorescence dip in the spectra (b) and (c) originates from conformers and , respectively. See the text for details.

Image of FIG. 2.
FIG. 2.

(Color online) Fully optimized structures of six conformers for 1-aminoindan calculated at the B3LYP/cc-pVTZ level.

Image of FIG. 3.
FIG. 3.

SVLF spectra following excitation of the bands at (a) , (b) , and (c) for conformer .

Image of FIG. 4.
FIG. 4.

SVLF spectra following excitation of the bands at (a) and (b) for conformer .

Image of FIG. 5.
FIG. 5.

SVLF spectra following excitation of the bands at (a) for conformer and (b) for conformer .

Tables

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Table I.

Frequencies and assignments for the transition of 1-aminoindan.

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Table II.

Calculated energies relative to the most stable conformer I.

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Table III.

Observed and calculated vibrational frequencies at the B3LYP/cc-pVTZ level and their assignments for conformers and .

Generic image for table
Table IV.

Fluorescene lifetime on the single vibronic level of 1-aminoindan and indan.

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/content/aip/journal/jcp/126/21/10.1063/1.2736687
2007-06-05
2014-04-19
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Low-frequency vibrations specific for conformers of 1-aminoindan studied by UV-UV hole-burning spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/126/21/10.1063/1.2736687
10.1063/1.2736687
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