1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Role of spatial distortions on the quadratic nonlinear optical properties of octupolar organic and metallo-organic molecules
Rent:
Rent this article for
USD
10.1063/1.2428308
    + View Affiliations - Hide Affiliations
    Affiliations:
    1 Laboratoire de Photonique Quantique et Moléculaire (CNRS UMR 8537), Institut d’Alembert (IFR 121), École normale Supérieure de Cachan, 61 Avenue du Président Wilson, 94235 Cachan, France
    2 “Organométalliques et Catalyse: Chimie et Electrochimie Moléculaires” (CNRS UMR 6509), Institut de Chimie de Rennes, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes, France
    a) Present address: Center for Nanophotonics, FOM Institute AMOLF, Kruislaan 407, 1098 SJ Amsterdam, The Netherlands. Electronic mail: sebastien.bidault@normalesup.org
    b) Present address: Institut Fresnel (UMR 6133), Universités Aix Marseille, Campus de Saint Jérôme, Avenue Escadrille Normandie 13397 Marseille Cedex 20, France.
    c) Present address: Laboratoire de Chimie (UMR 5182), ENS Lyon, 46 allée d’Italie, 69364 Lyon cedex 07, France.
    J. Chem. Phys. 126, 034312 (2007); http://dx.doi.org/10.1063/1.2428308
/content/aip/journal/jcp/126/3/10.1063/1.2428308
http://aip.metastore.ingenta.com/content/aip/journal/jcp/126/3/10.1063/1.2428308

Figures

Image of FIG. 1.
FIG. 1.

Several molecules whose nonlinear behaviors were recently studied by polarized HRS and/or AOP experiments. Molecule 1 was synthesized by Piron et al. (Ref. 32).

Image of FIG. 2.
FIG. 2.

(Color online) Neutral and zwiterionic (a) states of DR1 and VB-CT states of a octupole.

Image of FIG. 3.
FIG. 3.

(Color online) VB and CT states for (a) and (b) metallo-octupoles.

Image of FIG. 4.
FIG. 4.

(Color online) Schematic 3D representations of the complex [(a) and (b)] exhibiting four charge transfers (solid arrows). The two representations are linked by a rotation along . Energy ladder of the eigenvalues of with their corresponding irreducible labels in the group (c).

Image of FIG. 5.
FIG. 5.

(Color online) Schematic 3D representations of the right-[(a) and (b)] and left-handed [(c) and (d)] complexes exhibiting six charge transfers (solid arrows) in the working framework. Energy ladder of the eigenvalues of with their corresponding irreducible labels in the group (e).

Image of FIG. 6.
FIG. 6.

(Color online) Schematic representation of a distorted planar molecule in the working framework.

Image of FIG. 7.
FIG. 7.

(Color online) (a) Molecular anisotropy evolution with and (, , and ). (b) Detail of (a) with .

Image of FIG. 8.
FIG. 8.

(Color online) (a) Molecular anisotropy evolution with (, , , and ). (b) Molecular anisotropy evolution with and (, , and ).

Image of FIG. 9.
FIG. 9.

Different “all trans” conformations of molecule 1 with the corresponding values of for and 20°.

Image of FIG. 10.
FIG. 10.

(Color online) Distortion angles allowed in molecule 2 and new working framework.

Image of FIG. 11.
FIG. 11.

(Color online) Allowed distortions of one -conjugated arm of the bidentate ligand.

Image of FIG. 12.
FIG. 12.

(Color online) (a) Molecular anisotropy evolution with and (, , , and ). (b) Detail of (a) with .

Image of FIG. 13.
FIG. 13.

(Color online) (a) Molecular anisotropy evolution with (a) and (b) (, , , , and ).

Image of FIG. 14.
FIG. 14.

(Color online) Schematic 3D (a) and 2D (b) representations of a planar molecule exhibiting three charge transfers (solid arrows). Energy diagram of the VB-CT basis (c) and of the eigenvalues of the Hamiltonian (d).

Tables

Generic image for table
Table I.

Quadratic NLO behaviors of molecules 1 (Ref. 32), 2 (Ref. 47), and 3 (Ref. 29).

Loading

Article metrics loading...

/content/aip/journal/jcp/126/3/10.1063/1.2428308
2007-01-19
2014-04-24
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Role of spatial distortions on the quadratic nonlinear optical properties of octupolar organic and metallo-organic molecules
http://aip.metastore.ingenta.com/content/aip/journal/jcp/126/3/10.1063/1.2428308
10.1063/1.2428308
SEARCH_EXPAND_ITEM