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Asymmetric band profile of the Soret band of deoxymyoglobin is caused by electronic and vibronic perturbations of the heme group rather than by a doming deformation
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10.1063/1.2775931
/content/aip/journal/jcp/127/13/10.1063/1.2775931
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/13/10.1063/1.2775931

Figures

Image of FIG. 1.
FIG. 1.

Absorption spectra of (a) deoxyMb, (c) MbCN, and (e) aquametMb. CD spectra of (b) deoxyMb, (d) MbCN, and (f) aquametMb. Thick black line, experimental spectra and dashed line, simulated spectra.

Image of FIG. 2.
FIG. 2.

(Color online) Polarized resonance Raman spectra of deoxymyoglobin measured with excitation. Black solid line, spectrum taken with polarization parallel to the polarization of excitation. Red circle symbols, spectrum taken with polarization perpendicular to the polarization of excitation. The assignments of the major bands are indicated. The spectrum was corrected for self-absorption by using the method of Unger et al. (Ref. 38).

Tables

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Table I.

Depolarization ratios and relative intensities of resonance Raman bands measured with excitation.

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Table II.

Spectral and coupling parameters used for the simulation of the absorption and CD band profiles of the Soret band of deoxyMb.

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/content/aip/journal/jcp/127/13/10.1063/1.2775931
2007-10-04
2014-04-24
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Asymmetric band profile of the Soret band of deoxymyoglobin is caused by electronic and vibronic perturbations of the heme group rather than by a doming deformation
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/13/10.1063/1.2775931
10.1063/1.2775931
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