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Absorption spectra of (a) deoxyMb, (c) MbCN, and (e) aquametMb. CD spectra of (b) deoxyMb, (d) MbCN, and (f) aquametMb. Thick black line, experimental spectra and dashed line, simulated spectra.
(Color online) Polarized resonance Raman spectra of deoxymyoglobin measured with excitation. Black solid line, spectrum taken with polarization parallel to the polarization of excitation. Red circle symbols, spectrum taken with polarization perpendicular to the polarization of excitation. The assignments of the major bands are indicated. The spectrum was corrected for self-absorption by using the method of Unger et al. (Ref. 38).
Depolarization ratios and relative intensities of resonance Raman bands measured with excitation.
Spectral and coupling parameters used for the simulation of the absorption and CD band profiles of the Soret band of deoxyMb.
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