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Photoelectron spectroscopy of adiabatically bound valence anions of rare tautomers of the nucleic acid bases
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10.1063/1.2795719
/content/aip/journal/jcp/127/17/10.1063/1.2795719
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/17/10.1063/1.2795719
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Structures of anionic tautomers of pyrimidinic nucleic acid bases (U: top; T: middle; C: bottom). In each row the first entry illustrates the canonical tautomer and the next two illustrate new tautomers that result from the canonical tautomer through N-to-C proton transfers. The VDE values were obtained at the CCSD(T)/aug-cc-pVDZ level of theory.

Image of FIG. 2.
FIG. 2.

The photoelectron spectra of all five NAB parent anions.

Image of FIG. 3.
FIG. 3.

Comparison of photoelectron spectra of T (solid line) and U (dashed line).

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/content/aip/journal/jcp/127/17/10.1063/1.2795719
2007-11-07
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Photoelectron spectroscopy of adiabatically bound valence anions of rare tautomers of the nucleic acid bases
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/17/10.1063/1.2795719
10.1063/1.2795719
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