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Thermodynamics and kinetics of competing aggregation processes in a simple model system
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10.1063/1.2777137
/content/aip/journal/jcp/127/18/10.1063/1.2777137
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/18/10.1063/1.2777137
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Binary diagrams of (monomer adsorption rate/solution dimerization rate). (a) The horizontal and vertical axes represent intermonomer binding energy and monomer-surface binding energy, respectively; monomer diameter is fixed at . (b) Horizontal and vertical axes represent monomer diameter and intermonomer binding energy, respectively; monomer-surface binding energy is fixed at .

Image of FIG. 2.
FIG. 2.

Binary diagrams of (a) (surface dimerization rate/solution dimerization rate), (b) (surface trimer formation rate/solution trimer formation rate), and (c) (surface tetramer formation rate/solution tetramer formation rate) for monomer diameter of . The horizontal and vertical axes represent intermonomer binding energy and monomer-surface binding energy, respectively.

Image of FIG. 3.
FIG. 3.

Binary diagrams of (a) (surface dimerization rate/solution dimerization rate) and (b) (surface trimer formation rate/solution trimer formation rate) for monomer-surface binding energy of . The horizontal and the vertical axes represent monomer diameter and intermonomer binding energy, respectively.

Image of FIG. 4.
FIG. 4.

Binary diagrams of (monomer adsorption-desorption equilibrium constant/solution dimerization equilibrium constant); (a) Horizontal and vertical axes are intermolecular binding energy and monomer-surface binding energy; monomer diameter is ; (b) Horizontal and vertical axes are monomer diameter and intermonomer binding energy; surface binding energy is

Image of FIG. 5.
FIG. 5.

Plots of (surface dimerization equilibrium constant/solution dimerization equilibrium constant) (a) vs monomer diameter for intermonomer binding energy of and (b) vs intermonomer binding energy for monomer diameter of .

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/content/aip/journal/jcp/127/18/10.1063/1.2777137
2007-11-08
2014-04-25
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Thermodynamics and kinetics of competing aggregation processes in a simple model system
http://aip.metastore.ingenta.com/content/aip/journal/jcp/127/18/10.1063/1.2777137
10.1063/1.2777137
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