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High resolution and low-temperature photoelectron spectroscopy of an oxygen-linked fullerene dimer dianion:
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10.1063/1.2889384
/content/aip/journal/jcp/128/11/10.1063/1.2889384
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/11/10.1063/1.2889384
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Photoelectron spectra of at (a) , (b) , (c) , and (d) . The vertical lines in (a) represent vibrational features. Signals due to a C–C cleaved isomer are labeled.

Image of FIG. 2.
FIG. 2.

Pictures of the lowest unoccupied molecular orbital (LUMO) and of drawn with the MOLEKEL visualization package (Ref. 36).

Image of FIG. 3.
FIG. 3.

The first two detachment transitions (X and A) that can derive from the nearly degenerate triplet and singlet states of , as well as the measured detachment energies.

Image of FIG. 4.
FIG. 4.

Franck–Condon factor simulation for the transition between the state of and the state of . The Franck–Condon factors were convoluted with Gaussians of FWHM.

Image of FIG. 5.
FIG. 5.

Pictures of the highest occupied molecular orbital (HOMO) and of the C–C bond cleaved isomer.

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/content/aip/journal/jcp/128/11/10.1063/1.2889384
2008-03-18
2014-04-16
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: High resolution and low-temperature photoelectron spectroscopy of an oxygen-linked fullerene dimer dianion: C120O2−
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/11/10.1063/1.2889384
10.1063/1.2889384
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