1887
banner image
No data available.
Please log in to see this content.
You have no subscription access to this content.
No metrics data to plot.
The attempt to load metrics for this article has failed.
The attempt to plot a graph for these metrics has failed.
Ultrafast intermolecular dynamics of liquid water: A theoretical study on two-dimensional infrared spectroscopy
Rent:
Rent this article for
USD
10.1063/1.2903470
/content/aip/journal/jcp/128/15/10.1063/1.2903470
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/15/10.1063/1.2903470
View: Figures

Figures

Image of FIG. 1.
FIG. 1.

Schematic picture of third-order nonlinear response function. Three pulses are applied to the system and thus the third-order response function is expressed by a three-time correlation function of dipole moment.

Image of FIG. 2.
FIG. 2.

Third-order nonlinear response functions of liquid water at several waiting times.

Image of FIG. 3.
FIG. 3.

2D IR correlation spectra of intermolecular motion of liquid water at several waiting times. The tilt angle is defined as the angle between the axis and the nodal line of the libration peak as shown in (a).

Image of FIG. 4.
FIG. 4.

Waiting time dependence of the tilt angle. Open circles and solid triangles are the results of the presence and absence of the hindered translation motion, respectively.

Image of FIG. 5.
FIG. 5.

2D IR correlation spectra in the absence of the hindered translation motion.

Image of FIG. 6.
FIG. 6.

Waiting time dependence of the integrated off-diagonal peak intensity. The intensity is integrated over the ranges of and . Open circles and solid triangles are the results of the presence and absence of the hindered translation motion, respectively. The solid line is single exponential function with the decay time of .

Image of FIG. 7.
FIG. 7.

Feynman diagrams corresponding to the off-diagonal peak at (, ). 0, , and denotes the ground state and the excited states of the libration and low frequency motions, respectively. The system represented by the diagram (a) is in a coherent state during . The diagram (b) involves the population transfer from the state to the state during .

Image of FIG. 8.
FIG. 8.

Heterodyne transient grating signals of liquid water in the presence (a) and absence (b) of the hindered translation motion, respectively. (c) Waiting time dependence of the peak position of the libration peak. Open circles and solid triangles are the results in the presence and absence of the hindered translation motion, respectively. The solid line is single exponential function with the decay time of .

Loading

Article metrics loading...

/content/aip/journal/jcp/128/15/10.1063/1.2903470
2008-04-21
2014-04-18
Loading

Full text loading...

This is a required field
Please enter a valid email address
752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Ultrafast intermolecular dynamics of liquid water: A theoretical study on two-dimensional infrared spectroscopy
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/15/10.1063/1.2903470
10.1063/1.2903470
SEARCH_EXPAND_ITEM