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Cold and ultracold chemical reactions of and
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10.1063/1.2928804
/content/aip/journal/jcp/128/22/10.1063/1.2928804
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/22/10.1063/1.2928804

Figures

Image of FIG. 1.
FIG. 1.

Adiabatic energies of FHCl for the partial wave .

Image of FIG. 2.
FIG. 2.

cumulative reaction probability of reaction. The energy scale is in for an easier comparison with Fig. 1 of Ref. 36.

Image of FIG. 3.
FIG. 3.

reactive cross sections for the partial waves , and and their sum as functions of the incident kinetic energy.

Image of FIG. 4.
FIG. 4.

Convergence of the reaction probabilities for collisions with respect to at an energy of .

Image of FIG. 5.
FIG. 5.

Reactive cross sections for collisions for and partial waves from full close-coupling calculation and the coupled-states approximation (CSA). The CSA and full calculations give nearly indistinguishable results at ultralow energies (left panels).

Image of FIG. 6.
FIG. 6.

components of the reactive cross sections for partial waves to .

Image of FIG. 7.
FIG. 7.

reactive cross sections vs the collision energy.

Image of FIG. 8.
FIG. 8.

reactive cross sections of : comparison between a full calculation and CSA results.

Image of FIG. 9.
FIG. 9.

reactive cross sections of : comparison between a full calculation and CSA results.

Image of FIG. 10.
FIG. 10.

inelastic and reactive cross sections of . For comparison, results of collisions have also been included.

Image of FIG. 11.
FIG. 11.

reactive cross sections for collisions. The reactive cross sections for collisions are also included for comparison. The arrows indicate two collision energies for which rotationally resolved cross sections are presented in Fig. 12.

Image of FIG. 12.
FIG. 12.

state-to-state reactive cross sections of at a collision energy of (upper panel) and at a collision energy of (lower panel). The collision energies correspond to the values indicated by the two arrows in Fig. 11.

Image of FIG. 13.
FIG. 13.

reactive cross sections of (upper panel) and (lower panel) in the collision energy range of . The energies of the quasibound states of F⋯HCl or F⋯DCl are also plotted.

Tables

Generic image for table
Table I.

Numerical convergence test results for different parameters of the ABC code (Ref. 42) for the reaction for a collision energy of . refers to the partial wave and the parity , denotes the maximum rotational quantum number of the diatomic arrangements, is the matching distance, mtr represents the number of log-derivative propagation sectors, and refers to the reaction probability.

Generic image for table
Table II.

Same as Table I but for the reaction.

Generic image for table
Table III.

Same as Table I but for the reaction.

Generic image for table
Table IV.

Resonance positions in the cross sections of reaction and energies of quasibound states of the entrance channel van der Waals complexes obtained from bound state calculations. The energy reference for the quasibound states has been taken to be the energy of .

Generic image for table
Table V.

Same as Table IV but for reaction. The resonance positions correspond to quasibound states of van der Waals complexes. The energy reference for the quasibound states has been taken to be the energy of .

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/content/aip/journal/jcp/128/22/10.1063/1.2928804
2008-06-10
2014-04-17
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Cold and ultracold chemical reactions of F+HCl and F+DCl
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/22/10.1063/1.2928804
10.1063/1.2928804
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