Potential energy curves showing two conical intersections along the N–H bond dissociation coordinate. The crossing occurs at the planar geometry, where the plane is along the C–N axis.
Total translational energy distribution and anisotropy parameter values from the dissociation excited at the (a) ZPE, (b) , and (c) levels of the state.
Total translational energy distributions and anisotropy parameter values from the dissociation excited at the (a) ZPE, (b) , (c) , and (d) levels of the state.
Schematic diagram of the one-dimensional cut of the two-dimensional potential energy surface showing the CASSCF calculated geometry at the conical intersection. The N–H bond elongation axis is perpendicular to the paper.
Relative yields of the slow and fast components, maximum energies in the translational energy distribution, translational temperatures, and average kinetic energies measured at the zero-point state and states of and .
Calculated energetics of methylamines and methylamino radicals using the CCSD method for the ground state and the EOM-CCSD for the excited state.
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