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Mass spectrum showing the parent anion of adenosine--monophosphate, i.e. .
The photoelectron spectra of and , both recorded with photons. The arrows mark the experimentally determined VDE values, while for the spectrum, the solid vertical line denotes the theoretically determined VDE value and the dashed vertical line denotes the theoretically determined value.
Schematic showing the mechanism by which intramolecular, barrier-free, proton transfer takes place upon electron attachment to dAMPH. The last step depicts the result of photodetachment of an electron from the resulting anion, i.e., from structure IV.
Tabulation of experimental and theoretical adiabatic electron affinity and vertical detachment energy (VDE) values for the -dAMPH and -AMPH neutral/anion systems.
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