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Photoelectron spectroscopy of the parent anions of the nucleotides, adenosine--monophosphate and deoxyadenosine--monophosphate
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10.1063/1.2823001
/content/aip/journal/jcp/128/4/10.1063/1.2823001
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/4/10.1063/1.2823001

Figures

Image of FIG. 1.
FIG. 1.

Mass spectrum showing the parent anion of adenosine--monophosphate, i.e. .

Image of FIG. 2.
FIG. 2.

The photoelectron spectra of and , both recorded with photons. The arrows mark the experimentally determined VDE values, while for the spectrum, the solid vertical line denotes the theoretically determined VDE value and the dashed vertical line denotes the theoretically determined value.

Image of FIG. 3.
FIG. 3.

Schematic showing the mechanism by which intramolecular, barrier-free, proton transfer takes place upon electron attachment to dAMPH. The last step depicts the result of photodetachment of an electron from the resulting anion, i.e., from structure IV.

Tables

Generic image for table
Table I.

Tabulation of experimental and theoretical adiabatic electron affinity and vertical detachment energy (VDE) values for the -dAMPH and -AMPH neutral/anion systems.

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/content/aip/journal/jcp/128/4/10.1063/1.2823001
2008-01-30
2014-04-24
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752b84549af89a08dbdd7fdb8b9568b5 journal.articlezxybnytfddd
Scitation: Photoelectron spectroscopy of the parent anions of the nucleotides, adenosine-5′-monophosphate and 2′deoxyadenosine-5′-monophosphate
http://aip.metastore.ingenta.com/content/aip/journal/jcp/128/4/10.1063/1.2823001
10.1063/1.2823001
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